Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts
文献类型：期刊论文
| 作者 | Li, Zhenyu1; Huai, Liyuan1; Hao, Panpan1; Zhao, Xi1; Wang, Yongzhao2; Zhang, Bingsen2; Chen, Chunlin1; Zhang, Jian1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2022-03-01 |
| 卷号 | 43期号:3页码:793-801 |
| ISSN号 | 0253-9837 |
| 关键词 | 2,5-Bis(hydroxymethyl)furan 2,5-Furandicarboxylic acid Palladium hydride 5-Hydroxymethylfurfural Catalytic oxidation |
| DOI | 10.1016/S1872-2067(21)63878-0 |
| 通讯作者 | Hao, Panpan(haopanpan@nimte.ac.cn) ; Zhang, Jian(jzhang@nimte.ac.cn) |
| 英文摘要 | The selective oxidation of 2,5-bis(hydroxymethyl)furan (BHMF) in this work was proven as a promising route to produce 2,5-furandicarboxylic acid (FDCA), an emerging bio-based building-block with wide application. Under ambient pressure, the modified carbon nanotube-supported Pd-based catalysts demonstrate the maximum FDCA yield of 93.0% with a full conversion of BHMF after 60 min at 60 degrees C, much superior to that of the traditional route using 5-hydroxymethylfurfural (HMF) as substrates (only a yield of 35.7%). The participation of PdHx active species with metallic Pd can be responsible for the encouraging performance. Meanwhile, a possible reaction pathway proceeding through 2,5-diformylfuran (DFF) and 5-formyl-2-furancarboxylic acid (FFCA) as process intermediates is suggested for BHMF route. The present work may provide new opportunities to synthesize other high value-added oxygenates by using BHMF as an alternative feedstock. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 资助项目 | National Natural Science Foundation of China[22072170] ; Chinese Academy of Sciences[QYZDB-SSW-JSC037] ; Ningbo Science and Technology Bureau[2018B10056] ; Ningbo Science and Technology Bureau[2019B10096] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000788414700008 |
| 资助机构 | National Natural Science Foundation of China ; Chinese Academy of Sciences ; Ningbo Science and Technology Bureau |
| 源URL | [http://ir.imr.ac.cn/handle/321006/172611]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Hao, Panpan; Zhang, Jian |
| 作者单位 | 1.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhenyu,Huai, Liyuan,Hao, Panpan,et al. Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2022,43(3):793-801. |
| APA | Li, Zhenyu.,Huai, Liyuan.,Hao, Panpan.,Zhao, Xi.,Wang, Yongzhao.,...&Zhang, Jian.(2022).Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts.CHINESE JOURNAL OF CATALYSIS,43(3),793-801. |
| MLA | Li, Zhenyu,et al."Oxidation of 2,5-bis(hydroxymethyl)furan to 2,5-furandicarboxylic acid catalyzed by carbon nanotube-supported Pd catalysts".CHINESE JOURNAL OF CATALYSIS 43.3(2022):793-801. |
入库方式： OAI收割
来源：金属研究所
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