Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties
文献类型：期刊论文
| 作者 | Li, Zhenyu1,4; Zhao, Linmin2; Chen, Hui1; Liang, Xiao1; Ai, Xuan1; Xie, Zhoubing1; Li, Xiaotian4; Yang, Feng3; Liu, Hongyang2; Zou, Xiaoxin1 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2021-12-13 |
| 页码 | 5 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/d1cy02112e |
| 通讯作者 | Liu, Hongyang(liuhy@imr.ac.cn) ; Zou, Xiaoxin(xxzou@jlu.edu.cn) |
| 英文摘要 | Three crystal phases of Pd-B intermetallics, namely, Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reactions are studied. In both reactions, their catalytic activities are found to increase in the order Pd, Pd6B, Pd5B2 and Pd2B. This activity trend is strongly associated with the Pd(d)-B(s,p) orbital hybridization-regulated surface adsorption properties. |
| 资助项目 | National Natural Science Foundation of China (NSFC)[21922507] ; National Natural Science Foundation of China (NSFC)[21771079] ; National Natural Science Foundation of China (NSFC)[21901083] ; National Natural Science Foundation of China (NSFC)[22179046] ; Fok Ying Tung Education Foundation[161011] ; Fundamental Research Funds for the Central Universities, NSFC[21621001] ; 111 Project[B17020] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000747885300001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China (NSFC) ; Fok Ying Tung Education Foundation ; Fundamental Research Funds for the Central Universities, NSFC ; 111 Project |
| 源URL | [http://ir.imr.ac.cn/handle/321006/173617]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liu, Hongyang; Zou, Xiaoxin |
| 作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 4.Jilin Univ, Coll Mat Sci & Engn, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhenyu,Zhao, Linmin,Chen, Hui,et al. Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties[J]. CATALYSIS SCIENCE & TECHNOLOGY,2021:5. |
| APA | Li, Zhenyu.,Zhao, Linmin.,Chen, Hui.,Liang, Xiao.,Ai, Xuan.,...&Zou, Xiaoxin.(2021).Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties.CATALYSIS SCIENCE & TECHNOLOGY,5. |
| MLA | Li, Zhenyu,et al."Crystal phase-selective synthesis of intermetallic palladium borides and their phase-regulated (electro)catalytic properties".CATALYSIS SCIENCE & TECHNOLOGY (2021):5. |
入库方式： OAI收割
来源：金属研究所
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