中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 金属研究所
  3. 中国科学院金属研究所
Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics

文献类型：期刊论文

作者Wu, Genghuang1; Zhao, Linmin2,3; Zong, Mingsheng1; Yu, Peng1; Xie, Jingxin1; Da, Zhijian1; Liu, Hongyang2,3; Rong, Junfeng1
刊名JOURNAL OF COLLOID AND INTERFACE SCIENCE
出版日期2022-02-15
卷号608页码:1278-1285
关键词Graphene encapsulation 3d transition metal nanoparticles Chemoselective hydrogenation Anti-poisoning Nitroarenes
ISSN号0021-9797
DOI10.1016/j.jcis.2021.10.105
通讯作者Da, Zhijian(dazhijian.ripp@sinopec.com) ; Liu, Hongyang(liuhy@imr.ac.cn) ; Rong, Junfeng(rongjf.ripp@sinopec.com)
英文摘要Graphene encapsulating 3d transition metal nanoparticles (Ni, Co, Fe@G) are successfully fabricated through pyrolysis of complexes which are simply prepared via "acid-base reactions" between metal hydroxides and carboxylic acid such as citric acid. In particular, the Ni@G catalyst exhibits outstanding catalytic activity and selectivity (>99%) toward the reduction of various nitroaromatics under mild conditions (1 MPa H-2, 60 degrees C), even in the presence of poisons (CO and thiophene etc.). This "acid-base reactions" based method provides a facile and scalable approach to prepare graphene encapsulating 3d transition metals with wide ranges of applications. (C) 2021 Elsevier Inc. All rights reserved.
资助项目China Petrochemical Corporation[420043-4] ; China Petrochemical Corporation[420043-10] ; National Key R&D Program of China[2016YFA0204100] ; National Natural Science Foundation of China[91845201] ; National Natural Science Foundation of China[21961160722] ; National Natural Science Foundation of China[22072162] ; Liaoning Revitalization Talents Program[XLYC1907055] ; Dalian National Lab for Clean Energy, (DNL Cooperation Fund)[202001]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000744111100007
出版者ACADEMIC PRESS INC ELSEVIER SCIENCE
资助机构China Petrochemical Corporation ; National Key R&D Program of China ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Dalian National Lab for Clean Energy, (DNL Cooperation Fund)
源URL[http://ir.imr.ac.cn/handle/321006/173626]  
专题金属研究所_中国科学院金属研究所
通讯作者Da, Zhijian; Liu, Hongyang; Rong, Junfeng
作者单位1.SINOPEC, Res Inst Petr Proc, Beijing 100083, Peoples R China
2.Chinese Acad Sci Inst, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
推荐引用方式
GB/T 7714		 Wu, Genghuang,Zhao, Linmin,Zong, Mingsheng,et al. Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2022,608:1278-1285.
APA Wu, Genghuang.,Zhao, Linmin.,Zong, Mingsheng.,Yu, Peng.,Xie, Jingxin.,...&Rong, Junfeng.(2022).Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics.JOURNAL OF COLLOID AND INTERFACE SCIENCE,608,1278-1285.
MLA Wu, Genghuang,et al."Facile fabrication of graphene encapsulating 3d transition metal nanoparticles as highly active and anti-poisoning catalysts for selective hydrogenation of nitroaromatics".JOURNAL OF COLLOID AND INTERFACE SCIENCE 608(2022):1278-1285.

入库方式： OAI收割

来源：金属研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。