Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment
文献类型：期刊论文
| 作者 | Zhao, Bowen1,2,3; Li, Hailong1,3; Li, Zhengkun1,3; Ge, Shaofan1,2,3; Qin, Xindong4; Zhang, Shiming5; Wang, Aimin1,3; Zhang, Haifeng1,3; Zhu, Zhengwang1,3 |
| 刊名 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2021-12-30 |
| 卷号 | 95页码:158-166 |
| ISSN号 | 1005-0302 |
| 关键词 | Copper nanocomposites Metallic glasses Self-propagating combustion Catalytic degradation Electron transfer Organic dyes |
| DOI | 10.1016/j.jmst.2021.04.017 |
| 通讯作者 | Zhu, Zhengwang(zwzhu@imr.ac.cn) |
| 英文摘要 | The functional copper nanocomposites (Cu NCs) have received increasing attention in the environmental catalysis application for wastewater treatment due to their superior catalytic activity and reactivity. However, overcoming the pH limitations towards the neutral and alkaline wastewater remains a tricky challenge. In this work, we demonstrate a green strategy to synthesize Cu NCs with coexistence of active Cu, Cu2O and ZrO2 by self-propagating combustion of metallic glassy ribbons, which exhibit the extremely superior catalytic performance for degradation reaction, providing full conversion of organic dyes completely to the environmental friendly small species (efficiency > 99%) under acidic, neutral and alkaline conditions. Compared with all other catalysts developed thus far, the novel Cu NCs catalysts with more active sites present much enhanced catalytic capability of degradation efficiency without the use of any chemical reagents for neutral and alkaline organic dye solutions. The possible decomposition pathways of organic dyes for different pH systems were systematically investigated. More importantly, the two kinds of catalytic mechanism related to high reactivity of nanoscale Cu/Cu2O and strong oxidizing capability of activated OH/O-2 - radicals can also be successfully confirmed under different pH conditions. The green synthetic approach can be extended to design the various M-based nanocomposites (M = Fe, Co, Ni, Ag, Pd) as efficient catalysts for the functional applications of many chemical reactions. (C) 2021 Published by Elsevier Ltd on behalf of Chinese Society for Metals. |
| 资助项目 | National Natural Science Foundation of China[51801209] ; National Natural Science Foundation of China[51790484] ; Liaoning Revitalization Talents Program[XLYC1802078] ; Liaoning Revitalization Talents Program[XLYC1807062] ; fund of Qingdao[19-9-2-1-wz] |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| 出版者 | JOURNAL MATER SCI TECHNOL |
| WOS记录号 | WOS:000733965200005 |
| 资助机构 | National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; fund of Qingdao |
| 源URL | [http://ir.imr.ac.cn/handle/321006/173847]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhu, Zhengwang |
| 作者单位 | 1.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Inst Met Res, OCAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China 4.Liaoning Univ, Coll Chem, Inst Rare & Scattered Elements, Shenyang 110036, Peoples R China 5.Qingdao Yunlu Adv Mat Technol Co Ltd, Qingdao 266232, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Bowen,Li, Hailong,Li, Zhengkun,et al. Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,95:158-166. |
| APA | Zhao, Bowen.,Li, Hailong.,Li, Zhengkun.,Ge, Shaofan.,Qin, Xindong.,...&Zhu, Zhengwang.(2021).Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,95,158-166. |
| MLA | Zhao, Bowen,et al."Green strategy of scaleably synthesizing copper nanocomposites with remarkable catalytic activity for wastewater treatment".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 95(2021):158-166. |
入库方式： OAI收割
来源：金属研究所
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