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Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures
文献类型：期刊论文
| 作者 | Najafpour, Mohammad Mahdi2; Renger, Gernot3; Holynska, Malgorzata4,5; Moghaddam, Atefeh Nemati; Aro, Eva-Mari; Carpentier, Robert7; Nishihara, Hiroshi; Eaton-Rye, Julian J.; Shen, Jian-Ren ; Allakhverdiev, Suleyman I.
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| 刊名 | CHEMICAL REVIEWS
 |
| 出版日期 | 2016 |
| 卷号 | 116期号:5页码:2886-2936 |
| ISSN号 | 0009-2665 |
| DOI | 10.1021/acs.chemrev.5b00340 |
| 文献子类 | Review |
| 英文摘要 | All cyanobacteria, algae, and plants use a similar water-oxidizing catalyst for water oxidation. This catalyst is housed in Photosystem II, a membrane-protein complex that functions as a light-driven water oxidase in oxygenic photosynthesis. Water oxidation is also an important reaction in artificial photosynthesis because it has the potential to provide cheap electrons from water for hydrogen production or for the reduction of carbon dioxide on an industrial scale. The water-oxidizing complex of Photosystem II is a Mn-Ca cluster that oxidizes water with a low overpotential and high turnover frequency number of up to 25-90 molecules of O-2 released per second. In this Review, we discuss the atomic structure of the Mn-Ca cluster of the Photosystem II water-oxidizing complex from the viewpoint that the underlying mechanism can be informative when designing artificial water-oxidizing catalysts. This is followed by consideration of functional Mn-based model complexes for water oxidation and the issue of Mn complexes decomposing to Mn oxide. We then provide a detailed assessment of the chemistry of Mn oxides by considering how their bulk and nanoscale properties contribute to their effectiveness as water-oxidizing catalysts. |
| 学科主题 | Chemistry, Multidisciplinary |
| 出版地 | WASHINGTON |
| 电子版国际标准刊号 | 1520-6890 |
| WOS关键词 | OXYGEN-EVOLVING COMPLEX ; O-O BOND ; COUPLED ELECTRON-TRANSFER ; S-STATE TRANSITIONS ; SCHIFF-BASE COMPLEXES ; II CORE COMPLEXES ; CYANOBACTERIAL PHOTOSYSTEM-II ; FTIR DIFFERENCE SPECTROSCOPY ; OCTAHEDRAL MOLECULAR-SIEVES ; AMINO-ACID-RESIDUES |
| WOS研究方向 | Science Citation Index Expanded (SCI-EXPANDED) |
| 语种 | 英语 |
| WOS记录号 | WOS:000371947300003 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Institute for Advanced Studies in Basic Sciences ; National Elite Foundation ; Academy of FinlandAcademy of Finland [118637] ; JSPS, MEXT, JapanMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [24000018] ; Russian Science FoundationRussian Science Foundation (RSF) [14-14-00039] |
| 源URL | [http://ir.ibcas.ac.cn/handle/2S10CLM1/25322]  |
| 专题 | 中科院光生物学重点实验室 |
| 作者单位 | 1.Allakhverdiev, Suleyman I.] Moscow MV Lomonosov State Univ, Dept Plant Physiol, Fac Biol, Leninskie Gory 1-12, Moscow 119991, Russia 2.IASBS, Dept Chem, Zanjan 451951159, Iran 3.IASBS, Ctr Climate Change & Global Warming, Zanjan 451951159, Iran 4.Tech Univ Berlin, Inst Chem, Max Volmer Lab Biophys Chem, Str 17 Juni 135, D-10623 Berlin, Germany 5.Univ Marburg, Fachbereich Chem, Hans Meerwein Str, D-35032 Marburg, Germany 6.Univ Marburg, WZMW, Hans Meerwein Str, D-35032 Marburg, Germany 7.Univ Turku, Dept Biochem & Food Chem, FIN-20014 Turku, Finland 8.Univ Quebec Trois Rivieres, GRBV, CP 500, Trois Rivieres, PQ G9A 5H7, Canada 9.Nishihara, Hiroshi; Allakhverdiev, Suleyman I.] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan 10.Eaton-Rye, Julian J.] Univ Otago, Dept Biochem, POB 56, Dunedin 9054, New Zealand |
| 推荐引用方式 GB/T 7714 | Najafpour, Mohammad Mahdi,Renger, Gernot,Holynska, Malgorzata,et al. Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures[J]. CHEMICAL REVIEWS,2016,116(5):2886-2936. |
| APA | Najafpour, Mohammad Mahdi.,Renger, Gernot.,Holynska, Malgorzata.,Moghaddam, Atefeh Nemati.,Aro, Eva-Mari.,...&Allakhverdiev, Suleyman I..(2016).Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures.CHEMICAL REVIEWS,116(5),2886-2936. |
| MLA | Najafpour, Mohammad Mahdi,et al."Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures".CHEMICAL REVIEWS 116.5(2016):2886-2936. |
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来源：植物研究所
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