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Enhanced mechanical properties of epoxy composites embedded with MF/TiO2 hybrid shell microcapsules containing n-octadecane

文献类型：期刊论文

作者Peng, Guangjian3,4,5; Hu, Yahao5; Dou, Guijing5; Sun, Yiheng5; Huan, Yong1,2; Kang, Sung Hoon3,4; Piao, Zhongyu5; Xun Y(郇勇); Huan Y(郇勇)
刊名JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
出版日期2022-06-25
卷号110页码:414-423
ISSN号1226-086X
关键词In situ polymerization Hybrid shell microcapsules Microcapsule epoxy composites Interface strengthening
DOI10.1016/j.jiec.2022.03.018
通讯作者Kang, Sung Hoon(shkang@jhu.edu) ; Piao, Zhongyu(piaozy@zjut.edu.cn)
英文摘要Microencapsulated phase change materials (MPCMs) are often mixed with matrix materials to form phase change composites for energy storage. Typically, MPCMs are easily debonded from the matrix or ruptured, thereby weakening the mechanical properties of composites. This paper aims to simultaneously improve the rupture strength of microcapsules and the bonding strength between microcapsules and matrix to enhance the mechanical properties of composites. The titanium dioxide (TiO2) nanoparticles modified by a silane coupling agent (KH560) were doped into the melamine formaldehyde (MF) shell, forming n-octadecane@MF/TiO2 hybrid shell MPCMs (HS-MPCMs). The doping of modified TiO2 nanoparticles reduced supercooling and improved the thermal stability of microcapsules. Compared with MF microcapsules, the rupture strength of HS-MPCMs was increased by an average of 30.4%. The modified TiO2 nanoparticles also built covalent bonds between microcapsule shell and matrix, which led to better microcapsule/epoxy interface bonding. Thus, the HS-MPCMs/epoxy composites performed higher tensile strength than the unmodified composites. Specifically, the tensile strength of composites was improved by an average of 17.2% at the microcapsule content of 10 wt.% with the aid of the MF/TiO2 hybrid shell. The reinforced MPCMs/epoxy composites are expected to be used as anti-icing coatings in the aerospace field. (c) 2022 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
WOS关键词PHASE-CHANGE MATERIALS ; THERMAL-ENERGY STORAGE ; SURFACE MODIFICATION ; TITANIUM-DIOXIDE ; GRAPHENE OXIDE ; NANOPARTICLES ; PERFORMANCE ; FABRICATION ; POLYMERIZATION
资助项目National Natural Science Foundation of China[11772302] ; National Natural Science Foundation of China[12172332] ; National Natural Science Foundation of China[11727803] ; National Natural Science Foundation of China[11972037] ; Funda-mental Research Funds for the Provincial Universities of Zhejiang[RF-A2020013] ; Johns Hopkins University startup fund for Sung Hoon
WOS研究方向Chemistry ; Engineering
语种英语
WOS记录号WOS:000802137300011
资助机构National Natural Science Foundation of China ; Funda-mental Research Funds for the Provincial Universities of Zhejiang ; Johns Hopkins University startup fund for Sung Hoon
源URL[http://dspace.imech.ac.cn/handle/311007/89594]  
专题力学研究所_非线性力学国家重点实验室
通讯作者Kang, Sung Hoon; Piao, Zhongyu
作者单位1.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech LNM, Beijing 100190, Peoples R China
3.Johns Hopkins Univ, Hopkins Extreme Mat Inst, Baltimore, MD 21218 USA
4.Johns Hopkins Univ, Dept Mech Engn, Baltimore, MD 21218 USA
5.Zhejiang Univ Technol, Coll Mech Engn, Hangzhou 310023, Peoples R China
推荐引用方式
GB/T 7714		 Peng, Guangjian,Hu, Yahao,Dou, Guijing,et al. Enhanced mechanical properties of epoxy composites embedded with MF/TiO2 hybrid shell microcapsules containing n-octadecane[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2022,110:414-423.
APA Peng, Guangjian.,Hu, Yahao.,Dou, Guijing.,Sun, Yiheng.,Huan, Yong.,...&Huan Y.(2022).Enhanced mechanical properties of epoxy composites embedded with MF/TiO2 hybrid shell microcapsules containing n-octadecane.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,110,414-423.
MLA Peng, Guangjian,et al."Enhanced mechanical properties of epoxy composites embedded with MF/TiO2 hybrid shell microcapsules containing n-octadecane".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 110(2022):414-423.

入库方式： OAI收割

来源：力学研究所

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