中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment

文献类型:期刊论文

作者Zhang, Xuan4; Wang, Yanhua4; Zhang, Dongmei4; Tao, Zhencheng1,2,3
刊名FRONTIERS IN MATERIALS
出版日期2022-06-03
卷号9页码:12
关键词photocathodic protection CoNi-LDH Zno nanocluster 304 stainless steel electrochemical method
ISSN号2296-8016
DOI10.3389/fmats.2022.904555
通讯作者Wang, Yanhua(wyhazz@163.com) ; Tao, Zhencheng(taozc@qdio.ac.cn)
英文摘要In this study, two kinds of Co-Ni-layer double hydroxide (LDH)/ZnO films were prepared with different morphologies by a simple electrochemical method. The properties of the films were investigated by SEM, XRD, UV-Vis DRS, XPS, and electrochemical techniques. It was found that Co-Ni-LDH-modified ZnO films exhibited excellent photocathodic properties in a scavenger-free environment. This is mainly due to the absorption of visible light by LDH, the formation of p-n heterojunction, and the depletion of photo-generated holes by the cycling process of Co (II)/Co (III). Compared with CoNi-LDH/ZnO nanorods, CoNi-LDH/ZnO nanoclusters showed better photocathodic protection performance and physical barrier effect. Under illumination conditions, the rough surface of ZnO nanoclusters and the deposition of a large amount of LDH can provide more photoelectrochemical active sites, thus improving the light absorption capacity and photocathodic protection performance of CoNi-LDH/ZnO nanoclusters. Under dark conditions, the physical barrier effect of CoNi-LDH/ZnO nanoclusters was also enhanced by the dense ZnO nanoclusters and thick CoNi-LDH layers.
资助项目National Natural Science Foundation of China[42090044] ; National Natural Science Foundation of China[KEXUE 2018G17]
WOS研究方向Materials Science
语种英语
WOS记录号WOS:000812754200001
出版者FRONTIERS MEDIA SA
源URL[http://ir.qdio.ac.cn/handle/337002/179148]  
专题海洋研究所_海洋生态与环境科学重点实验室
通讯作者Wang, Yanhua; Tao, Zhencheng
作者单位1.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao, Peoples R China
2.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Ecol & Environm Sci, Qingdao, Peoples R China
3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Ecol & Environm Sci, Qingdao, Peoples R China
4.Ocean Univ China, Coll Chem & Chem Engn, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Xuan,Wang, Yanhua,Zhang, Dongmei,et al. A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment[J]. FRONTIERS IN MATERIALS,2022,9:12.
APA Zhang, Xuan,Wang, Yanhua,Zhang, Dongmei,&Tao, Zhencheng.(2022).A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment.FRONTIERS IN MATERIALS,9,12.
MLA Zhang, Xuan,et al."A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment".FRONTIERS IN MATERIALS 9(2022):12.

入库方式: OAI收割

来源:海洋研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。