A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment
文献类型:期刊论文
作者 | Zhang, Xuan4; Wang, Yanhua4; Zhang, Dongmei4; Tao, Zhencheng1,2,3 |
刊名 | FRONTIERS IN MATERIALS
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出版日期 | 2022-06-03 |
卷号 | 9页码:12 |
关键词 | photocathodic protection CoNi-LDH Zno nanocluster 304 stainless steel electrochemical method |
ISSN号 | 2296-8016 |
DOI | 10.3389/fmats.2022.904555 |
通讯作者 | Wang, Yanhua(wyhazz@163.com) ; Tao, Zhencheng(taozc@qdio.ac.cn) |
英文摘要 | In this study, two kinds of Co-Ni-layer double hydroxide (LDH)/ZnO films were prepared with different morphologies by a simple electrochemical method. The properties of the films were investigated by SEM, XRD, UV-Vis DRS, XPS, and electrochemical techniques. It was found that Co-Ni-LDH-modified ZnO films exhibited excellent photocathodic properties in a scavenger-free environment. This is mainly due to the absorption of visible light by LDH, the formation of p-n heterojunction, and the depletion of photo-generated holes by the cycling process of Co (II)/Co (III). Compared with CoNi-LDH/ZnO nanorods, CoNi-LDH/ZnO nanoclusters showed better photocathodic protection performance and physical barrier effect. Under illumination conditions, the rough surface of ZnO nanoclusters and the deposition of a large amount of LDH can provide more photoelectrochemical active sites, thus improving the light absorption capacity and photocathodic protection performance of CoNi-LDH/ZnO nanoclusters. Under dark conditions, the physical barrier effect of CoNi-LDH/ZnO nanoclusters was also enhanced by the dense ZnO nanoclusters and thick CoNi-LDH layers. |
资助项目 | National Natural Science Foundation of China[42090044] ; National Natural Science Foundation of China[KEXUE 2018G17] |
WOS研究方向 | Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000812754200001 |
出版者 | FRONTIERS MEDIA SA |
源URL | [http://ir.qdio.ac.cn/handle/337002/179148] ![]() |
专题 | 海洋研究所_海洋生态与环境科学重点实验室 |
通讯作者 | Wang, Yanhua; Tao, Zhencheng |
作者单位 | 1.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao, Peoples R China 2.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Ecol & Environm Sci, Qingdao, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Ecol & Environm Sci, Qingdao, Peoples R China 4.Ocean Univ China, Coll Chem & Chem Engn, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xuan,Wang, Yanhua,Zhang, Dongmei,et al. A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment[J]. FRONTIERS IN MATERIALS,2022,9:12. |
APA | Zhang, Xuan,Wang, Yanhua,Zhang, Dongmei,&Tao, Zhencheng.(2022).A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment.FRONTIERS IN MATERIALS,9,12. |
MLA | Zhang, Xuan,et al."A Comparative Study of CoNi-LDH/ZnO Film for Photocathodic Protection Applications in the Marine Environment".FRONTIERS IN MATERIALS 9(2022):12. |
入库方式: OAI收割
来源:海洋研究所
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