Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties
文献类型：期刊论文
| 作者 | Sun, Jiawen1,2,4,5; Duan, Jizhou1,2,4,5; Liu, Xiangju1,2,4; Dong, Xucheng1,2,4,5 ; Zhang, Yimeng1,2,4; Liu, Chao3,4; Hou, Baorong1,2,4,5
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| 刊名 | APPLIED MATERIALS TODAY
 |
| 出版日期 | 2022-08-01 |
| 卷号 | 28页码:19 |
| ISSN号 | 2352-9407 |
| 关键词 | Self-healing Hydrogen bonding Disulfide bond Antifouling Anti-corrosion |
| DOI | 10.1016/j.apmt.2022.101551 |
| 通讯作者 | Duan, Jizhou(duanjz@qdio.ac.cn) ; Liu, Chao(liuchao@hunau.edu.cn) |
| 英文摘要 | Marine corrosion and biofouling on metallic materials are sticky problems in maintenance of various vessels and facilities in the ocean. Further, designing of an eco-friendly marine coating with both antifouling and anticorrosion properties has remained a significant challenge in marine field. The present study aimed to develop a novel smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties was through disulfide exchange reaction between the functionalized monomer "lipoic acid-benzothiazole" (LA-BTZ) and LA modified polydimethylsiloxane (PDMS) based polyurea-urethane (PDMS-PUU-LA). Multiple dynamic bonds in backbone, flexible disulfide bonds, and strong cross-linked hydrogen bonds ensure the PDMS-based polymer with good toughness (2.58 MPa of ultimate strength), high stretchability (1014.7%), and self-healing properties. It was found that the scratches on the film in air completely disappeared within 40 min at room temperature. The time required for the healing efficiency of strength ranged between 98.5 and 94.6% under ambient condition and artificial seawater was only 4 and 8 h, respectively. The adhesion strength of silicon-based coating to epoxy resin and steel substrate was -2.50 and -3.33 MPa, respectively. In addition, results of laboratory bioassays and marine field test of 120-day demonstrated that coating without any additional toxic biocides in the present study had long-term static fouling-resistant properties. Electrochemical impedance spectroscopy (EIS) measurements and salt spray test showed that the PDMS-PUU-TZ-3 coating exhibited the better corrosion resistance. Therefore, the current work presented a novel eco-friendly smart silicone-based coating for marine antifouling and anticorrosion. |
| 资助项目 | Basic Frontier Science Research Program of Chinese Academy of Sciences[ZDBS-LY-DQC025] ; National Natural Science Foundation of China[41706080] ; Shandong Key Laboratory of Corrosion Science |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000812689100001 |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/179536]  |
| 专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
| 通讯作者 | Duan, Jizhou; Liu, Chao |
| 作者单位 | 1.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 168 Wenhai Middle Rd, Qingdao 266237, Peoples R China 2.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China 3.Hunan Agr Univ, Coll Resources & Environm, 1 Nongda Rd, Changsha 410128, Peoples R China 4.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 5.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Jiawen,Duan, Jizhou,Liu, Xiangju,et al. Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties[J]. APPLIED MATERIALS TODAY,2022,28:19. |
| APA | Sun, Jiawen.,Duan, Jizhou.,Liu, Xiangju.,Dong, Xucheng.,Zhang, Yimeng.,...&Hou, Baorong.(2022).Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties.APPLIED MATERIALS TODAY,28,19. |
| MLA | Sun, Jiawen,et al."Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties".APPLIED MATERIALS TODAY 28(2022):19. |
入库方式： OAI收割
来源：海洋研究所
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