Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes
文献类型：期刊论文
| 作者 | Yu, Wan-Jing5; Liu, Fan5; Zhang, Lili4; Liu, Zhiyuan5; Wang, Sumei3; Tong, Hui1,2,5 |
| 刊名 | CARBON
 |
| 出版日期 | 2022-08-30 |
| 卷号 | 196页码:92-101 |
| 关键词 | Zn-MOF Microscale carbon cube Lithiophilic ZnO Metallic Li anodes Homogeneous nucleation |
| ISSN号 | 0008-6223 |
| DOI | 10.1016/j.carbon.2022.04.045 |
| 通讯作者 | Tong, Hui(huitong@csu.edu.cn) |
| 英文摘要 | The high energy density metallic Li anode is a desired electrode candidate for commercial application in future. However, uncontrolled growth of Li dendrites can easily lead to thermal runaway and infinite volume changes. Herein, we propose the addition of lithiophilic ZnO filled into the microsized cubic carbon framework through in situ pyrolyzation of the multiwalled carbon nanotubes-implanted Zn-MOF (denoted as ZnO@C-MWCNTs) as the three-dimensional (3D) host for stable metallic Li anodes. The proposed 3D host with a high specific surface area can effectively accommodate the tremendous volume change of the metallic Li anodes. Meanwhile, this 3D host can prohibit the emergence of Li dendrites by adjusting the local current density. Lithiophilic ZnO, as the homogeneous nucleation site loaded in the 3D structure, can induce homogeneous Li deposition to form a stable Li metal composite electrode with a long cycling life. The 3D ZnO@C-MWCNTs host can hold a high Coulombic efficiency (CE) of 98.5% at 1.0 mA cm-2 and 1.0 mAh cm-2 for more than 240 cycles. Long lifespans of symmetric cells for 320 h at 2.0 mA cm-2 and 1.0 mAh cm-2 with a lower polarization (~28.0 mV) can be achieved. |
| 资助项目 | Natural Science Foundation of Hunan Province[2019JJ50814] ; Science and Technology Innovation Program of Hunan Province[2020SK2007] ; Fundamental Research Funds for Central Universities of the Central South University[2021zzts0606] |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000804037300001 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | Natural Science Foundation of Hunan Province ; Science and Technology Innovation Program of Hunan Province ; Fundamental Research Funds for Central Universities of the Central South University |
| 源URL | [http://ir.imr.ac.cn/handle/321006/174149]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Tong, Hui |
| 作者单位 | 1.Cent South Univ, Natl Engn Res Ctr Low Carbon Nonferrous Met, Changsha 410083, Peoples R China 2.Cent South Univ, Engn Res Ctr Minist Educ Adv Battery Mat, Changsha 410083, Peoples R China 3.Cent South Univ, Powder Met Inst, Changsha 410083, Peoples R China 4.Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 5.Cent South Univ, Sch Met & Environm, Changsha 410083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Wan-Jing,Liu, Fan,Zhang, Lili,et al. Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes[J]. CARBON,2022,196:92-101. |
| APA | Yu, Wan-Jing,Liu, Fan,Zhang, Lili,Liu, Zhiyuan,Wang, Sumei,&Tong, Hui.(2022).Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes.CARBON,196,92-101. |
| MLA | Yu, Wan-Jing,et al."Lithiophilic ZnO confined in microscale carbon cubes as a stable host for lithium metal anodes".CARBON 196(2022):92-101. |
入库方式： OAI收割
来源：金属研究所
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