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Facile fabrication of 3D flower-like V2Al1-xCTz as an anode for lithium-ion batteries

文献类型：期刊论文

作者Liu, Rui Jia2,3; Yang, Ling Xu1; Lin, Guang Qiang1; Zhang, Tian Yu2,3; Bu, Huan Peng1; Liu, Hui Jun1; Zeng, Chao Liu1
刊名JOURNAL OF ALLOYS AND COMPOUNDS
出版日期2022-07-05
卷号908页码:10
关键词V2AlC Molten salt Flower-like V(2)Al(1-x)CTz Lithium-ion batteries Anode
ISSN号0925-8388
DOI10.1016/j.jallcom.2022.164596
通讯作者Liu, Hui Jun(hui_jun_liu@163.com) ; Zeng, Chao Liu(clzeng@imr.ac.cn)
英文摘要Herein, the 3D flower-like V2Al1-xCTz with an estimated petaloid nanosheet thickness of 10-20 nm were firstly obtained by etching the submicro-sized V2AlC precursors, which were synthesized at 1000 ? holding for 5 h in (Na,K)Cl melt by a facile molten salt method, in 40 wt% HF at room temperature. The synthesis mechanism of V2AlC is possibly related to the disproportionation reaction of V-ions on carbon surface in molten salts to form V2C, followed by the intercalation of Al into V2C. Subsequently, the 3D flower-like V(2)Al(1-x)CTz was applied as an anode in lithium-ion batteries, releasing ~215.2 mA h g(-1) in the continuous 500 cycles at 0.5 A g(-1), which exhibits the superiority in the reversible capacity in contrast with some reported micro-sized layered V(2)CTz MXenes. Such excellent electrochemical characteristics of V(2)Al(1-x)CTz could be mainly ascribed to its unique submicro-sized flower-like morphology with high specific surface areas and abundant electrochemical sites for accommodating the reversible insertion/extraction of Li-ions. (C) 2022 Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[51671204]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000806389200002
出版者ELSEVIER SCIENCE SA
资助机构National Natural Science Foundation of China
源URL[http://ir.imr.ac.cn/handle/321006/174353]  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Hui Jun; Zeng, Chao Liu
作者单位1.Songshan Lake Mat Lab, Dongguan 523808, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Rui Jia,Yang, Ling Xu,Lin, Guang Qiang,et al. Facile fabrication of 3D flower-like V2Al1-xCTz as an anode for lithium-ion batteries[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2022,908:10.
APA Liu, Rui Jia.,Yang, Ling Xu.,Lin, Guang Qiang.,Zhang, Tian Yu.,Bu, Huan Peng.,...&Zeng, Chao Liu.(2022).Facile fabrication of 3D flower-like V2Al1-xCTz as an anode for lithium-ion batteries.JOURNAL OF ALLOYS AND COMPOUNDS,908,10.
MLA Liu, Rui Jia,et al."Facile fabrication of 3D flower-like V2Al1-xCTz as an anode for lithium-ion batteries".JOURNAL OF ALLOYS AND COMPOUNDS 908(2022):10.

入库方式： OAI收割

来源：金属研究所

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