Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters
文献类型：期刊论文
| 作者 | Sun, Yu-Tuo1,2,3; Rao, Xiaofeng2,3; Xu, Weici2,3; Xu, Ming-Hua2,3 |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2022-05-10 |
| 页码 | 6 |
| ISSN号 | 2052-4129 |
| DOI | 10.1039/d2qo00164k |
| 通讯作者 | Xu, Ming-Hua(xumh@sustech.edu.cn) |
| 英文摘要 | Asymmetric construction of C-S bonds through transition-metal catalysis is a challenging subject. By using chiral diene as the ligand, we have developed the first rhodium(i)-catalyzed asymmetric carbene insertion approach for C-S bond formation to access sulfur-substituted stereocenters under mild conditions, allowing the facile synthesis of a range of potentially valuable alpha-thioesters in high yields with moderate to good enantioselectivities. |
| WOS关键词 | METALLO-BETA-LACTAMASE ; FDA-APPROVED DRUGS ; THIOMANDELIC ACID ; SULFUR ; CYCLOPROPANATION ; ACTIVATION ; INHIBITOR ; ALKENES ; ACCESS |
| 资助项目 | National Natural Science Foundation of China[21971103] ; Shenzhen Science and Technology Innovation Commission[JCYJ20200109141408054] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000796594700001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/301107]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Xu, Ming-Hua |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, 555 Chongzhi Rd, Shanghai 201203, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, 1088 Xueyuan Blvd, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, 1088 Xueyuan Blvd, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yu-Tuo,Rao, Xiaofeng,Xu, Weici,et al. Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters[J]. ORGANIC CHEMISTRY FRONTIERS,2022:6. |
| APA | Sun, Yu-Tuo,Rao, Xiaofeng,Xu, Weici,&Xu, Ming-Hua.(2022).Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters.ORGANIC CHEMISTRY FRONTIERS,6. |
| MLA | Sun, Yu-Tuo,et al."Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of alpha-thioesters".ORGANIC CHEMISTRY FRONTIERS (2022):6. |
入库方式： OAI收割
来源：上海药物研究所
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