A facile electrosynthesis of N-acyl benzotriazoles from aldehydes and benzotriazole
文献类型：期刊论文
| 作者 | Feng, Jianling2; Wang, Qiang1; Duan, Ruomeng2; Li, Huadeng2; Zheng, Ke2; Wang, Xiaoxia2; Xie, Guanqun2 |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2022-07-06 |
| 卷号 | 101页码:4 |
| ISSN号 | 0040-4039 |
| 关键词 | N -acyl benzotriazoles Electrosynthesis Aldehyde One-pot Esterification |
| DOI | 10.1016/j.tetlet.2022.153904 |
| 通讯作者 | Wang, Xiaoxia(wangxx@dgut.edu.cn) ; Xie, Guanqun(gqxie@dgut.edu.cn) |
| 英文摘要 | An electrochemical synthesis of N-acylbenzotriazoles has been developed under mild conditions with good to excellent yields using aldehydes and benzotriazole as starting materials. In addition, a one-pot reaction of aldehyde, benzotriazole and phenol has been achieved affording phenolic esters in moderate yields under the combination of electricity-on/off conditions, where N-acyl benzotriazole acted as the benign acylating reagent. It is noteworthy the research provided environmental friendly syntheses in that no superstoichiometric hazardous chemical oxidants were required, corrosive/toxic reagents have been avoided and waste production has significantly been reduced. The key of the electrochemical synthesis involves the oxidation of benzotriazole-aldehyde adduct by phthalimido-N-oxy (PINO), which was generated by N-hydroxyphthalimide (NHPI) as a redox mediator. (c) 2022 Elsevier Ltd. All rights reserved. |
| WOS关键词 | ACYLBENZOTRIAZOLES ; AMIDES ; DERIVATIVES ; SECONDARY |
| 资助项目 | Basic and Applied Basic Research Foundation of Guangdong Province[2019A1515110551] ; Science Foundation for Distinguished Scholars of Dongguan University of Technology[211135283] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| WOS记录号 | WOS:000817816100006 |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/301818]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Wang, Xiaoxia; Xie, Guanqun |
| 作者单位 | 1.Chinese Acad Sci, Zhongshan Inst Drug Discovery, Shanghai Inst Mat Med, Zhongshan 528400, Peoples R China 2.Dongguan Univ Technol, Guangdong Prov Engn Technol Res Ctr, Sch Environm & Civil Engn, Key Mat High Performance Copper Clad Laminate, Dongguan 523808, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Jianling,Wang, Qiang,Duan, Ruomeng,et al. A facile electrosynthesis of N-acyl benzotriazoles from aldehydes and benzotriazole[J]. TETRAHEDRON LETTERS,2022,101:4. |
| APA | Feng, Jianling.,Wang, Qiang.,Duan, Ruomeng.,Li, Huadeng.,Zheng, Ke.,...&Xie, Guanqun.(2022).A facile electrosynthesis of N-acyl benzotriazoles from aldehydes and benzotriazole.TETRAHEDRON LETTERS,101,4. |
| MLA | Feng, Jianling,et al."A facile electrosynthesis of N-acyl benzotriazoles from aldehydes and benzotriazole".TETRAHEDRON LETTERS 101(2022):4. |
入库方式： OAI收割
来源：上海药物研究所
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