Catalytic enhancement of small sizes of CeO2 additives on Ir/Al2O3 for toluene oxidation
文献类型：期刊论文
| 作者 | Wang, Zhiqiang1; Zhang, Lixin1; Ji, Jiawei1; Wu, Yuchao2; Cai, Yandi1; Yao, Xiaojiang3 ; Gu, Xianrui2; Xiong, Yan4; Wan, Haiqin1; Dong, Lin1
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| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2022 |
| 卷号 | 571页码:11 |
| 关键词 | Iridium catalyst Ceria additives Toluene catalytic oxidation Interaction |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2021.151200 |
| 通讯作者 | Wan, Haiqin(wanhq@nju.edu.cn) |
| 英文摘要 | Catalytic combustion of VOCs is one of the most promising technologies for removal of VOCs. Developing new and highly performance catalyst is very important for the application of this technology. Here, we report the fabrication of catalysts Ir/Ce/gamma-Al2O3 for complete oxidation of toluene, via confining the particles size of CeO2 additives. The catalysts are analyzed by XRD, H-2-TPR, O-2-TPD, TEM, HRTEM, XPS, Raman and in-situ DRIFTS. The catalyst Ir/Ce(A)/Al2O3 contains small CeO2 nanoparticles (<5 nm) loaded with ultrafine nanoparticles of Ir-0 (<2 nm), exhibiting higher catalytic activity for toluene oxidation than the control catalyst with large CeO2 additives. The results from XRD, TEM, Raman and XPS show the formation of a strong interaction between the IrO2 and the small CeO2 nanoparticles, resulting in the enhanced catalytic activity. This novel means for synthesizing the iridium-based catalyst promises the catalytic oxidation of VOCs. |
| 资助项目 | National Natural Science Foundation of China[21976082] ; National Natural Science Foundation of China[21972062] ; National Key Research and Development Program of China[2016YFC0204301] ; Key Research and Development Program of Jiangsu Province of China[BE2019118] |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000728581100004 |
| 出版者 | ELSEVIER |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/14710]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Wan, Haiqin |
| 作者单位 | 1.Nanjing Univ, Jiangsu Key Lab Vehicle Emiss Control, State Key Lab Pollut Control & Resource Reuse, Sch Environm,Sch Chem & Chem Engn, Nanjing 210023, Peoples R China 2.Sinopec, Res Inst Petr Proc, Beijing 100083, Peoples R China 3.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Key Lab Reservoir Aquat Environm CAS, Res Ctr Atmospher Environm, Chongqing 400714, Peoples R China 4.Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Peoples R China 5.Natl Cent Univ, Dept Chem Engn, Jhong Li 32001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zhiqiang,Zhang, Lixin,Ji, Jiawei,et al. Catalytic enhancement of small sizes of CeO2 additives on Ir/Al2O3 for toluene oxidation[J]. APPLIED SURFACE SCIENCE,2022,571:11. |
| APA | Wang, Zhiqiang.,Zhang, Lixin.,Ji, Jiawei.,Wu, Yuchao.,Cai, Yandi.,...&Chen, Yu-Wen.(2022).Catalytic enhancement of small sizes of CeO2 additives on Ir/Al2O3 for toluene oxidation.APPLIED SURFACE SCIENCE,571,11. |
| MLA | Wang, Zhiqiang,et al."Catalytic enhancement of small sizes of CeO2 additives on Ir/Al2O3 for toluene oxidation".APPLIED SURFACE SCIENCE 571(2022):11. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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