Mass transfer effect to electrochemical reduction of CO2: Electrode, electrocatalyst and electrolyte
文献类型:期刊论文
作者 | Lu, Shun1; Wang, Yucheng2; Xiang, Hang3; Lei, Hanhui2; Bin Xu, Ben2; Xing, Lei4; Yu, Eileen Hao3,4; Liu, Terence Xiaoteng2 |
刊名 | JOURNAL OF ENERGY STORAGE |
出版日期 | 2022-08-01 |
卷号 | 52页码:20 |
关键词 | Electrochemically CO 2 reduction Mass transfer Electrode Electrocatalyst Electrolyte |
DOI | 10.1016/j.est.2022.104764 |
通讯作者 | Yu, Eileen Hao(e.yu@lboro.ac.uk) ; Liu, Terence Xiaoteng(Terence.liu@northumbria.ac.uk) |
英文摘要 | Electrochemical carbon dioxide reduction reaction (eCO2RR) to value-added chemicals is considered as a promising strategy for CO2 conversion with economic and environmental benefits. Recently, investigations in eCO2RR to produce chemicals as energy or chemical industrial feedstock have received much attention. The eCO2RR generally occurs at the interface between electrode/electrocatalyst and electrolyte including charge transfer, phase transformation and mass transport. One of key problems in the electrochemical reaction is mass transfer limitation owing to the gaseous property of CO2 with low concentration on the surface of electrode/ electrocatalyst. Several strategies were employed to improve mass transfer in the past years, including electrochemical reactors, electrodes, electrocatalysts and electrolytes, etc. which could low reaction barriers so adequately that reaction rates can be realized that are sufficient for eCO2RR. This article comprehensively reviewed development related to mass transfer study of CO2, including the mechanism of mass transfer of CO2, and main factors (electrodes, electrocatalysts and electrolytes) on two-phase or multi-phase interface during eCO2RR. The article is not aim at providing a comprehensive review of technical achievements towards eCO2RR technology, but rather to highlight electrode, catalyst, electrolyte, and other factors, which can understand the above components or factors' effects towards mass transfer investigations, to decouple mass transfer limitations and improve the performance of electrochemical CO2 conversion. Furthermore, the challenges and perspectives for mass transfer to eCO2RR are proposed. |
资助项目 | UK Engineering Physics and Science Research Council[EP/S032886/1] ; Royal Society In-ternational Exchanges Award[IEC/NSFC/201008] |
WOS研究方向 | Energy & Fuels |
语种 | 英语 |
出版者 | ELSEVIER |
WOS记录号 | WOS:000798158600002 |
源URL | [http://119.78.100.138/handle/2HOD01W0/16272] |
专题 | 中国科学院重庆绿色智能技术研究院 |
通讯作者 | Yu, Eileen Hao; Liu, Terence Xiaoteng |
作者单位 | 1.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China 2.Northumbria Univ, Fac Engn & Environm, Newcastle Upon Tyne NE1 8ST, Northumberland, England 3.Newcastle Univ, Sch Engn, Newcastle Upon Tyne NE1 7RU, Northumberland, England 4.Loughborough Univ, Dept Chem Engn, Loughborough LE11 3TU, Leics, England |
推荐引用方式 GB/T 7714 | Lu, Shun,Wang, Yucheng,Xiang, Hang,et al. Mass transfer effect to electrochemical reduction of CO2: Electrode, electrocatalyst and electrolyte[J]. JOURNAL OF ENERGY STORAGE,2022,52:20. |
APA | Lu, Shun.,Wang, Yucheng.,Xiang, Hang.,Lei, Hanhui.,Bin Xu, Ben.,...&Liu, Terence Xiaoteng.(2022).Mass transfer effect to electrochemical reduction of CO2: Electrode, electrocatalyst and electrolyte.JOURNAL OF ENERGY STORAGE,52,20. |
MLA | Lu, Shun,et al."Mass transfer effect to electrochemical reduction of CO2: Electrode, electrocatalyst and electrolyte".JOURNAL OF ENERGY STORAGE 52(2022):20. |
入库方式: OAI收割
来源:重庆绿色智能技术研究院
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。