A New Copper(I) Complex Based on Imidazole and Triphenylphosphine Ligands: Synthesis, Structure, Third-Order NLO, and Fluorescence Properties
文献类型：期刊论文
| 作者 | Liu Faqian1; Jin Yanling1; Liu Baocheng1; Li Rongxun1; Deng Yueyi1; Li Weihua2; Jian Fangfang3 |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2012-05-01 |
| 卷号 | 30期号:5页码:1069-1074 |
| 关键词 | third-order NLO properties luminescence TD-DFT copper(I) complex |
| ISSN号 | 1001-604X |
| 通讯作者 | Liu, FQ (reprint author), Qingdao Univ Sci & Technol, Minist Educ, Engn Res Ctr High Performance Polymer & Molding T, Qingdao 266042, Shandong, Peoples R China. |
| 英文摘要 | A new candidate [Cu(PPh3)2Him]Br (1, PPh3=triphenylphosphine, Him=1-H-imidazole) for nonlinear optical (NLO) materials has been synthesized and characterized crystallographically. The third-order NLO optical properties were measured by the Z-scan technique with an 8 ns pulsed laser at 532 nm. Compound 1 exhibits strong NLO absorptive abilities [a2=(61 +/- 5) x 10(-12)] and effective self-focusing performance [n2=(15 +/- 3) x 10(-18) m2.W-1] in 1.01 x 10(-4) mol.dm(-3) DMF solution. The compound also exhibits luminescence in DMF solution at room temperature and shows narrow emission with maximum at 382 nm. The electronic structure and photoluminescent process were investigated by means of TD-DFT calculations. The results suggest that the contribution to the frontier orbitals from the Cu?Br d bond plays a crucial role in its linear optical properties, and the origin of luminescence is attributable to the p*??n transitions. |
| 学科主题 | Chemistry, Multidisciplinary |
| 收录类别 | SCI |
| 原文出处 | 10.1002/cjoc.201100581 |
| 语种 | 英语 |
| WOS记录号 | WOS:000304045600011 |
| 公开日期 | 2013-09-24 |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/12456]  |
| 专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
| 作者单位 | 1.Qingdao Univ Sci & Technol, Minist Educ, Engn Res Ctr High Performance Polymer & Molding T, Qingdao 266042, Shandong, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Shandong, Peoples R China 3.Qingdao Univ Sci & Technol, New Mat & Funct Coordinat Chem Lab, Qingdao 266042, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Faqian,Jin Yanling,Liu Baocheng,et al. A New Copper(I) Complex Based on Imidazole and Triphenylphosphine Ligands: Synthesis, Structure, Third-Order NLO, and Fluorescence Properties[J]. CHINESE JOURNAL OF CHEMISTRY,2012,30(5):1069-1074. |
| APA | Liu Faqian.,Jin Yanling.,Liu Baocheng.,Li Rongxun.,Deng Yueyi.,...&Jian Fangfang.(2012).A New Copper(I) Complex Based on Imidazole and Triphenylphosphine Ligands: Synthesis, Structure, Third-Order NLO, and Fluorescence Properties.CHINESE JOURNAL OF CHEMISTRY,30(5),1069-1074. |
| MLA | Liu Faqian,et al."A New Copper(I) Complex Based on Imidazole and Triphenylphosphine Ligands: Synthesis, Structure, Third-Order NLO, and Fluorescence Properties".CHINESE JOURNAL OF CHEMISTRY 30.5(2012):1069-1074. |
入库方式： OAI收割
来源：海洋研究所
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