Direct synthesis of methane-rich gas from reed biomass pyrolysis volatiles over its biochar-supported Ni catalysts
文献类型:期刊论文
作者 | Yue, Xia2,3; Chen, Dezhen3; Luo, Jia3; Huang, Zhen1; Hong, Liu3; Hu, Yuyan3 |
刊名 | BIOMASS & BIOENERGY |
出版日期 | 2021-11-01 |
卷号 | 154页码:11 |
ISSN号 | 0961-9534 |
关键词 | Reed Biochar-supported Ni catalyst Pyrolysis volatiles Methane-rich gas Inorganic salt |
DOI | 10.1016/j.biombioe.2021.106250 |
通讯作者 | Chen, Dezhen(chendezhen@tongji.edu.cn) |
英文摘要 | Thermochemical conversion of biomass into methane is a promising way for bioenergy recovery and alleviate natural gas shortage; however, the available technologies are queried by the complex procedures. This paper proposed a new approach for the direct synthesis of methane-rich gases from reed pyrolysis volatile at atmospheric pressure, according to which the reed pyrolysis volatiles are catalyzed over reed biochar-supported Ni catalysts in two stages to be converted. Seawater and freshwater reeds were compared for preparing effective catalysts, and the influences of inorganic salts in reed biomass on the catalytic performance were explored. The reed biochar-supported Ni catalysts were also compared with gamma-Al2O3-supported Ni catalyst (Ni/gamma-Al2O3) to evaluate their activities. It has been found that freshwater reed biochar-supported Ni catalysts (Ni/FWBs) performed better than seawater reed biochar-supported catalysts (Ni/SWBs) and Ni/gamma-Al2O3 owing to their large specific surface areas, uniform Ni particle dispersions, and appropriate Ni/biochar interactions. The Ni/FWB with biochar support produced at 600 degrees C (Ni/600FWB) was the best, and its corresponded tar-free gas product was characterized by a methane yield of 188.38 L/kg( reed) after two-stage catalytic conversion. The SWBs with higher alkali metal contents corresponded to larger Ni loading amounts than that of FWBs under the same conditions; however, they suffered from Ni particle aggregation and fusion, which deteriorated their catalytic activities. The findings indicated that the inexpensive Ni/FWBs were effective for the direct synthesis of methane from biomass pyrolysis volatiles, and the approach developed in this study provides an alternative to produce methane from biomass economically. |
WOS关键词 | NI/AL2O3 CATALYSTS ; GASIFICATION ; ALKALI ; TEMPERATURE ; NICKEL ; DECOMPOSITION ; TOLUENE ; ROLES |
资助项目 | Chinese national key research program[2017YFC0506004] |
WOS研究方向 | Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000705972000004 |
资助机构 | Chinese national key research program |
源URL | [http://ir.giec.ac.cn/handle/344007/35065] |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Chen, Dezhen |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, CAS, Guangzhou, Peoples R China 2.Inner Mongolia Univ Technol, Sch Mech Engn, 49 Aimin Rd, Hohhot 010051, Peoples R China 3.Tongji Univ, Thermal & Environm Engn Inst, Sch Mech Engn, 1239 Siping Rd, Shanghai 200092, Peoples R China |
推荐引用方式 GB/T 7714 | Yue, Xia,Chen, Dezhen,Luo, Jia,et al. Direct synthesis of methane-rich gas from reed biomass pyrolysis volatiles over its biochar-supported Ni catalysts[J]. BIOMASS & BIOENERGY,2021,154:11. |
APA | Yue, Xia,Chen, Dezhen,Luo, Jia,Huang, Zhen,Hong, Liu,&Hu, Yuyan.(2021).Direct synthesis of methane-rich gas from reed biomass pyrolysis volatiles over its biochar-supported Ni catalysts.BIOMASS & BIOENERGY,154,11. |
MLA | Yue, Xia,et al."Direct synthesis of methane-rich gas from reed biomass pyrolysis volatiles over its biochar-supported Ni catalysts".BIOMASS & BIOENERGY 154(2021):11. |
入库方式: OAI收割
来源:广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。