A review on recent developments in N-methylation using CO2
文献类型：期刊论文
| 作者 | Lin, Shanshan2,3; Liu, Jianguo1; Ma, Longlong1,3
|
| 刊名 | JOURNAL OF CO2 UTILIZATION
 |
| 出版日期 | 2021-12-01 |
| 卷号 | 54页码:18 |
| 关键词 | CO2 N-methylation N-methylamine N, N-dimethylamine Catalyst DNA methylation |
| ISSN号 | 2212-9820 |
| DOI | 10.1016/j.jcou.2021.101759 |
| 通讯作者 | Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| 英文摘要 | Owing to the increasing emissions of carbon dioxide (CO2) in recent years, people's interest in the use of CO2, especially the synthesis of value-added chemicals with CO2 as a C1 blocking, has also increased year by year. In particular, the N-methylation reaction of CO2 to synthesize amines has attracted widespread attention. As an important raw material for chemical synthesis, methylation products have a wide range of uses in industry and even in nature. Using CO2 to replace traditional methylation reagents is not only green and environmentally friendly but also reduces costs. To overcome the thermodynamic and kinetic stability of CO2 and improve the selectivity and conversion rate of the N-methylation reaction, researchers are committed to the development of high-efficiency catalysts such as noble metal-supported or homogeneous catalysts, non-noble metals such as Cu, Ni, Zn, and some new metal-free catalysts. This paper summarizes and reviews the research progress and applications in the high-efficiency catalyst systems and catalytic reaction process conditions of CO2 and H-2 (or organosilane) and amines to form N-methylamine and N, N-dimethylamine compounds in recent years. It is expected to provide a reference for the development of new processes for the catalytic conversion of CO2 into high value-added chemicals. |
| WOS关键词 | METAL-FREE CATALYST ; CARBON-DIOXIDE ; REDUCTIVE FUNCTIONALIZATION ; IONIC LIQUIDS ; AMINES ; HYDROGENATION ; FORMYLATION ; METHANOL ; HYDROSILANES ; EFFICIENT |
| 资助项目 | National Natural Science Foundation of China[51976225] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000711394500002 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/35171]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Jianguo; Ma, Longlong |
| 作者单位 | 1.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Shanshan,Liu, Jianguo,Ma, Longlong. A review on recent developments in N-methylation using CO2[J]. JOURNAL OF CO2 UTILIZATION,2021,54:18. |
| APA | Lin, Shanshan,Liu, Jianguo,&Ma, Longlong.(2021).A review on recent developments in N-methylation using CO2.JOURNAL OF CO2 UTILIZATION,54,18. |
| MLA | Lin, Shanshan,et al."A review on recent developments in N-methylation using CO2".JOURNAL OF CO2 UTILIZATION 54(2021):18. |
入库方式： OAI收割
来源：广州能源研究所
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