Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst
文献类型：期刊论文
| 作者 | Song, Xiangbo2,3,4; Liao, Yuhe4; Zhu, Yuting2,4; Sun, Pengyao2,4; Chen, Lungang4; Ma, Longlong4 ; Yang, Hongwei1; Wang, Chenguang4
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| 刊名 | ENERGY & FUELS
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| 出版日期 | 2021-10-21 |
| 卷号 | 35期号:20页码:16665-16676 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.1c02693 |
| 通讯作者 | Yang, Hongwei(hyang@eri.org.cn) ; Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| 英文摘要 | Highly effective production of 5-hydroxymethylfurfural (HMF) from biobased sugar is one of the vital steps for the synthesis of a fuel precursor. In this work, a slow-release effect of proton from a heterogeneous catalyst induced by 1-butyl-3methylimidazole chloride ([Bmim]Cl) ionic liquids was found and employed to effectively convert biobased fructose to HMF. Under mild conditions of 100 degrees C and 60 min, a promising HMF yield of 94.6% with a fructose conversion of 99.1% could be achieved in a tetrahydrofuran solvent over the synergy of Amberlyst-15 with [Bmim]Cl, owing to the slow-release effect. Based on extensive control experiments and characterizations, a mechanism of slow release of proton induced by [Bmim]Cl was proposed to better understand the catalytic performance, mainly involving that proton in the -SO3H group of Amberlyst-15 was gradually replaced by the [Bmim]+ of the [Bmim]Cl additive. Additionally, the effect of various parameters (e.g., different ionic liquids and solvents, the loading of the ionic liquid and catalyst, and reaction temperature and time) was systematically investigated. Meanwhile, the stability of Amberlyst-15 and [Bmim]Cl was tested; both could be reused four times. This work provides a novel and highly effective strategy for conversion of biomass-based feedstock toward fuel precursors. |
| WOS关键词 | ION-EXCHANGE-RESIN ; HYDROXYMETHYLFURFURAL HMF ; EFFICIENT CONVERSION ; ASSISTED DEHYDRATION ; FORMIC ACIDS ; LIQUIDS ; GLUCOSE ; SYSTEM ; HYDROLYSIS ; BIOMASS |
| 资助项目 | National Key R&D Program of China[2019YFD1100601] ; National Key R&D Program of China[2018YFB1501504] ; National Natural Science Foundation of China[51776206] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000711024500027 |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program |
| 源URL | [http://ir.giec.ac.cn/handle/344007/35177]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yang, Hongwei; Wang, Chenguang |
| 作者单位 | 1.Natl Dev & Reform Commiss, Energy Res Inst, Acad Macroecon, Beijing 100038, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chuxiong Normal Univ, Sch Phys & Elect Sci, Chuxiong 675099, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Xiangbo,Liao, Yuhe,Zhu, Yuting,et al. Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst[J]. ENERGY & FUELS,2021,35(20):16665-16676. |
| APA | Song, Xiangbo.,Liao, Yuhe.,Zhu, Yuting.,Sun, Pengyao.,Chen, Lungang.,...&Wang, Chenguang.(2021).Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst.ENERGY & FUELS,35(20),16665-16676. |
| MLA | Song, Xiangbo,et al."Highly Effective Production of 5-Hydroxymethylfurfural from Fructose with a Slow-Release Effect of Proton of a Heterogeneous Catalyst".ENERGY & FUELS 35.20(2021):16665-16676. |
入库方式： OAI收割
来源：广州能源研究所
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