Integrated Full-Spectrum Solar Energy Catalysis for Zero-Emission Ethylene Production from Bioethanol
文献类型：期刊论文
| 作者 | Deng, Yu8,9; Batmunkh, Munkhbayar7; Ye, Liqun8,9; Song, Chenjie8,9; Ge, Teng6; Xu, Yixue8,9; Mu, Xiaoyang8,9; Liu, Wei8,9; Jin, Xiaoli6; Wong, Po Keung5 |
| 刊名 | ADVANCED FUNCTIONAL MATERIALS
 |
| 出版日期 | 2021-12-01 |
| 页码 | 9 |
| 关键词 | bioethanol defective tungsten oxide solar energy catalysis solar thermal synergy |
| ISSN号 | 1616-301X |
| DOI | 10.1002/adfm.202110026 |
| 通讯作者 | Ye, Liqun(lqye@ctgu.edu.cn) ; Ma, Tianyi(tianyima@swin.edu.au) |
| 英文摘要 | Ethylene, a hydrocarbon (C2H4), is one of the widely used products in the chemical industry. A traditional dehydration method of ethanol to ethylene relies strongly on high-temperature and high-pressure process with significant energy consumption. In this regard, producing ethylene from bioethanol through dehydration is a promising and sustainable approach, but, this process under mild conditions results in low yields and poor selectivity. Herein, an integrated solar energy catalytic system driven by only sun energy under ambient conditions is established for the first time for bioethanol dehydration using oxygen-vacancy-abundant (O-v) WO3 coupled with a thin layer of carbon coating (C-L) (WO3-x@C). A record-high ethylene selectivity of 98.1% is achieved driven by full solar spectrum without any external power, featuring zero pollution emission nature. In this process, O-v acts as a solid acid center, which is the key to initiate the dehydration of ethanol to ethylene via a solar thermal process, while the C-L promotes solar thermal synergy, ensuring the high reaction temperature and hot carriers transmission simultaneously. In-situ infrared spectroscopy and thermodynamic calculations demonstrate a novel proton hydrogen-mediated catalytic process over WO3-x@C. This work provides a new opportunity of using full-spectrum solar energy for catalytic generation of value-added chemicals. |
| WOS关键词 | ETHANOL DEHYDRATION ; CONVERSION ; DFT ; HYDROCARBONS ; MECHANISM ; METHANOL |
| 资助项目 | National Natural Science Foundation of China[51872147] ; 111 Project[D20015] ; research Fund for Excellent Dissertation of China Three Gorges University ; Australian Research Council (ARC)[FT210100298] ; CSIRO Energy Centre ; Victorian Government from veski - Study Melbourne Research Partnerships (SMRP) project ; CSIRO Kick-Start Project |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000724055600001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; 111 Project ; research Fund for Excellent Dissertation of China Three Gorges University ; Australian Research Council (ARC) ; CSIRO Energy Centre ; Victorian Government from veski - Study Melbourne Research Partnerships (SMRP) project ; CSIRO Kick-Start Project |
| 源URL | [http://ir.giec.ac.cn/handle/344007/35339]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Ye, Liqun; Ma, Tianyi |
| 作者单位 | 1.RMIT Univ, Sch Sci, Melbourne, Vic 3000, Australia 2.Swinburne Univ Technol, Ctr Translat Atomat, Hawthorn, Vic 3122, Australia 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.China Univ Geosci, Sch Mat Sci & Technol, Natl Lab Mineral Mat, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Beijing 100083, Peoples R China 5.Chinese Univ Hong Kong, Sch Life Sci, Shatin, Hong Kong, Peoples R China 6.Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China 7.Griffith Univ, Sch Environm & Sci, Ctr Catalysis & Clean Energy, Gold Coast, Qld 4222, Australia 8.Hubei Three Gorges Lab, Yichang 443007, Hubei, Peoples R China 9.China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Yichang 443002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Yu,Batmunkh, Munkhbayar,Ye, Liqun,et al. Integrated Full-Spectrum Solar Energy Catalysis for Zero-Emission Ethylene Production from Bioethanol[J]. ADVANCED FUNCTIONAL MATERIALS,2021:9. |
| APA | Deng, Yu.,Batmunkh, Munkhbayar.,Ye, Liqun.,Song, Chenjie.,Ge, Teng.,...&Ma, Tianyi.(2021).Integrated Full-Spectrum Solar Energy Catalysis for Zero-Emission Ethylene Production from Bioethanol.ADVANCED FUNCTIONAL MATERIALS,9. |
| MLA | Deng, Yu,et al."Integrated Full-Spectrum Solar Energy Catalysis for Zero-Emission Ethylene Production from Bioethanol".ADVANCED FUNCTIONAL MATERIALS (2021):9. |
入库方式： OAI收割
来源：广州能源研究所
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