Adsorption-Enhanced Glucan Oligomer Production from Cellulose Hydrolysis over Hyper-Cross-Linked Polymer in Molten Salt Hydrate
文献类型：期刊论文
| 作者 | Liu, Qiyu4; Zhou, Liang4; Fan, Di4; Guan, Mingzhao3; Ma, Qiaozhi3; Li, Song2; Ouyang, Xinping4; Qiu, Xueqing4; Fan, Wei1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2021-11-10 |
| 卷号 | 13期号:44页码:52082-52091 |
| 关键词 | cellulose hydrolysis glucan oligomer hyper-cross-linked polymer reactive adsorption |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.1c09360 |
| 通讯作者 | Ouyang, Xinping(ceouyang@scut.edu.cn) ; Qiu, Xueqing(cexqqiu@scut.edu.cn) ; Fan, Wei(wfan@engin.umass.edu) |
| 英文摘要 | Selective saccharification of cellulose into glucose is a critical step for utilization of lignocellulosic biomass. Molten salt hydrates (MSHs) have shown promising performance in selectively converting cellulose into glucose because of the high solubility of cellulose in the solvent. However, the separation of formed glucose from the MSHs is still a grand challenge. To address this issue, we developed a two-step process, where crystalline cellulose is hydrolyzed into short-chain glucan oligomers in MSHs followed by separation and subsequent hydrolysis of the formed oligomers into glucose under mild conditions. The two-step method provides an easy separation for glucan oligomers from the MSHs without sacrificing the selectivity to glucose. Application of the method for crystalline cellulose is, however, limited to a relatively low concentration, 26.2 mg/mL, because of the formation of byproducts in the MSH that facilitate oligomers degradation. In this work, reactive adsorption was employed to in situ remove the byproducts formed during cellulose hydrolysis in the MSH. It was found that hyper-cross-linked polymer (HCP) made from the polymerization of 4-vinylbenzyl chloride and divinylbenzene can selectively adsorb 5-hydroxymethylfurfural (5-HMF) and levulinic acid (LA) while showing negligible sugar adsorption in both water and the MSH. With the reactive adsorption approach, byproducts including 5-HMF and LA were removed from the reaction media under reaction conditions, and their negative effects on oligomer degradation were inhibited. In the presence of the HCP, the obtained glucan oligomer concentration was enhanced from less than 54.2 to 247.1 mg mL(-1) when the weight ratio of cellulose was increased to MSH from 1:60 to 1:4, exhibiting an oligomer yield of 69.5%. The HCP can be effectively separated from the reaction media by filtration and regenerated by oxidation with hydrogen peroxide. Application of reactive adsorption with HCP for cellulose hydrolysis in the MSH provides a promising method to produce glucan oligomers and glucose with an improved yield and efficiency. |
| WOS关键词 | GLUCOSE ; DISSOLUTION ; FRUCTOSE ; SOLVENTS |
| 资助项目 | National Key Research and Development Program of China[2019YFC1905301] ; National Natural Science Foundation of China[22008078] ; National Natural Science Foundation of China[51906072] ; National Natural Science Foundation of China[22078115] ; Catalysis Center for Energy Innovation - US Department of Energy, Office of Science, and Office of Basic Energy Sciences[DE-SC0001004] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000718271300029 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; Catalysis Center for Energy Innovation - US Department of Energy, Office of Science, and Office of Basic Energy Sciences |
| 源URL | [http://ir.giec.ac.cn/handle/344007/35342]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Ouyang, Xinping; Qiu, Xueqing; Fan, Wei |
| 作者单位 | 1.Univ Massachusetts, Dept Chem Engn, Amherst, MA 01003 USA 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 3.South China Agr Univ, Coll Mat & Energy, Guangzhou 510642, Peoples R China 4.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 233022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Qiyu,Zhou, Liang,Fan, Di,et al. Adsorption-Enhanced Glucan Oligomer Production from Cellulose Hydrolysis over Hyper-Cross-Linked Polymer in Molten Salt Hydrate[J]. ACS APPLIED MATERIALS & INTERFACES,2021,13(44):52082-52091. |
| APA | Liu, Qiyu.,Zhou, Liang.,Fan, Di.,Guan, Mingzhao.,Ma, Qiaozhi.,...&Fan, Wei.(2021).Adsorption-Enhanced Glucan Oligomer Production from Cellulose Hydrolysis over Hyper-Cross-Linked Polymer in Molten Salt Hydrate.ACS APPLIED MATERIALS & INTERFACES,13(44),52082-52091. |
| MLA | Liu, Qiyu,et al."Adsorption-Enhanced Glucan Oligomer Production from Cellulose Hydrolysis over Hyper-Cross-Linked Polymer in Molten Salt Hydrate".ACS APPLIED MATERIALS & INTERFACES 13.44(2021):52082-52091. |
入库方式： OAI收割
来源：广州能源研究所
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