Efficient hydrogenation catalyst designing via preferential adsorption sites construction towards active copper
文献类型：期刊论文
| 作者 | BSRF用户 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2021 |
| 卷号 | 400页码:397--406 |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2021.06.025 |
| 文献子类 | Article |
| 英文摘要 | Based on the experimental and DFT calculation results, here for the first time we built preferential adsorption sites for nitroarenes by modification of the supported Cu catalysts surface with 1,10phenathroline (1,10-phen), by which the yield of aniline via reduction of nitroarene is enhanced three times. Moreover, a macromolecular layer was in-situ generated on supported Cu catalysts to form a stable macromolecule modified supported Cu catalyst, i.e., CuAlOx-M. By applying the CuAlOx-M, a wide variety of nitroarene substrates react smoothly to afford the desired products in up to > 99% yield with > 99% selectivity. The method tolerates a variety of functional groups, including halides, ketone, amide, and C = C bond moieties. The excellent catalytic performance of the CuAlOx-M can be attributed to that the 1,10-phen modification benefits the preferential adsorption of nitrobenzene and slightly weakens adsorption of aniline on the supported nano-Cu surface. (c) 2021 Elsevier Inc. All rights reserved. |
| 电子版国际标准刊号 | 1090-2694 |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000678544000010 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/293465]  |
| 专题 | 北京同步辐射装置 |
| 推荐引用方式 GB/T 7714 | BSRF用户. Efficient hydrogenation catalyst designing via preferential adsorption sites construction towards active copper[J]. JOURNAL OF CATALYSIS,2021,400:397--406. |
| APA | BSRF用户.(2021).Efficient hydrogenation catalyst designing via preferential adsorption sites construction towards active copper.JOURNAL OF CATALYSIS,400,397--406. |
| MLA | BSRF用户."Efficient hydrogenation catalyst designing via preferential adsorption sites construction towards active copper".JOURNAL OF CATALYSIS 400(2021):397--406. |
入库方式： OAI收割
来源：高能物理研究所
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