Axial ligand promoted phosphate tolerance of an atomically dispersed Fe catalyst towards the oxygen reduction reaction
文献类型：期刊论文
| 作者 | Liu, Jing6; Wang, Jie6; Zhang, Linjuan5; Fan, Chaohua6; Zhou, Xin4; Zhang, Bingsen3; Cui, Xuejing6; Wang, Jianqiang5; Cheng, Yi2,4; Sun, Shuhui1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2022-08-10 |
| 卷号 | 10期号:31页码:16722-16729 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/d2ta03312g |
| 通讯作者 | Wang, Jianqiang(wangjianqiang@sinap.ac.cn) ; Cheng, Yi(yi.cheng@csu.edu.cn) ; Jiang, Luhua(luhuajiang@qust.edu.cn) |
| 英文摘要 | Developing active, stable and phosphate anion resistant catalysts is critical for high-temperature proton exchange membrane fuel cells based on phosphoric acid-doped polybenzimidazole (PA-PBI) membranes. Herein, an iron catalyst with a five-coordinated Fe active center is elaborately designed. The experimental and theoretical studies show that the planar Fe-N-4 moiety with an axial O ligand, benefiting from the optimized charge redistribution, weakens phosphate anion adsorption on Fe active centers and simultaneously promotes oxygen molecule dissociation, resulting in excellent phosphate anion tolerance and ORR activity with the half-wave potential remaining at 0.81 V. The axial-ligand promoted Fe-N-C catalyst is assembled for the first time in a PA-PBI fuel cell, delivering a decent performance. This study sheds light on the intrinsic cause for the phosphate anion tolerance of Fe-N-C catalysts at a molecular level, which provides guidance for designing highly active and stable electrocatalysts for PA-PBI fuel cells. |
| 资助项目 | Natural Science Foundation of China[U19A2016] ; Natural Science Foundation of China[21805156] ; Key Research and Development Project of Shandong Province[2019JZZY020809] ; Taishan Scholar Program of Shandong Province[ts201712046] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000834933000001 |
| 资助机构 | Natural Science Foundation of China ; Key Research and Development Project of Shandong Province ; Taishan Scholar Program of Shandong Province |
| 源URL | [http://ir.imr.ac.cn/handle/321006/174638]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wang, Jianqiang; Cheng, Yi; Jiang, Luhua |
| 作者单位 | 1.Ctr Energie Mat & Telecommun, Inst Natl Rech Sci INRS, Varennes, PQ J3X 1P7, Canada 2.Cent South Univ, Sch Met & Environm, Dept Environm Engn, Changsha 410083, Peoples R China 3.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China 4.Dalian Univ, Coll Environm & Chem Engn, Dalian 116622, Peoples R China 5.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China 6.Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Electrocatalysis & Nanomat Lab, Qingdao 266042, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jing,Wang, Jie,Zhang, Linjuan,et al. Axial ligand promoted phosphate tolerance of an atomically dispersed Fe catalyst towards the oxygen reduction reaction[J]. JOURNAL OF MATERIALS CHEMISTRY A,2022,10(31):16722-16729. |
| APA | Liu, Jing.,Wang, Jie.,Zhang, Linjuan.,Fan, Chaohua.,Zhou, Xin.,...&Jiang, Luhua.(2022).Axial ligand promoted phosphate tolerance of an atomically dispersed Fe catalyst towards the oxygen reduction reaction.JOURNAL OF MATERIALS CHEMISTRY A,10(31),16722-16729. |
| MLA | Liu, Jing,et al."Axial ligand promoted phosphate tolerance of an atomically dispersed Fe catalyst towards the oxygen reduction reaction".JOURNAL OF MATERIALS CHEMISTRY A 10.31(2022):16722-16729. |
入库方式： OAI收割
来源：金属研究所
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