Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis
文献类型：期刊论文
| 作者 | Yu, Zhipeng5,6,7; Si, Chaowei4; Javier Escobar-Bedia, Francisco3; LaGrow, Alec P.7; Xu, Junyuan2; Sabater, Maria J.3; Amorim, Isilda7; Araujo, Ana5,6,7; Sousa, Juliana P. S.7; Meng, Lijian1 |
| 刊名 | INORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2022-06-24 |
| 页码 | 9 |
| ISSN号 | 2052-1553 |
| DOI | 10.1039/d2qi00892k |
| 通讯作者 | Li, Bo(boli@imr.ac.cn) ; Liu, Lifeng(lifeng.liu@inl.int) |
| 英文摘要 | Atomically dispersed catalysts (ADCs) have recently drawn considerable interest for use in water electrolysis to produce hydrogen, because they allow for maximal utilization of metal species, particularly the expensive and scarce platinum group metals. Herein, we report the electrocatalytic performance of atomically dispersed ruthenium catalysts (Ru ADCs) with ultralow Ru loading (0.2 wt%). The as-obtained Ru ADCs (Ru (0.2)-NC) are active for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), which only require a low overpotential (eta) of 47.1 and 72.8 mV to deliver 10 mA cm(-2) for HER in 0.5 M H2SO4 and 1.0 M KOH, respectively, and of 300 mV for OER in 1.0 M KOH, showing favorable bifunctionality. Density functional theory (DFT) calculations reveal that the Ru-N bonding plays an important role in lowering the energy barrier of the reactions, boosting the HER and OER activities. Furthermore, the bipolar membrane (BPM) water electrolysis using the bifunctional Ru (0.2)-NC as both HER and OER catalysts can afford 10 mA cm(-2) under a low cell voltage of only 0.89 V, and does not show any performance decay upon 100 h continuous operation, showing great potential for energy-saving hydrogen production. |
| 资助项目 | National Innovation Agency of Portugal[POCI-01-0247-FEDER-046109] ; Natural Science Foundation of LiaoNing Province, China[20180510014] ; China Scholarship Council[201806150015] ; FCT/MCTES (PIDDAC)[LA/P/0045/2020] ; FCT/MCTES (PIDDAC)[UIDB/50020/2020] ; FCT/MCTES (PIDDAC)[UIDP/50020/2020] ; 2DMAT4FUEL (COMPETE2020 - FCT/MCTES - PIDDAC, Portugal)[POCI-01-0145-FEDER-029600] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000819504900001 |
| 资助机构 | National Innovation Agency of Portugal ; Natural Science Foundation of LiaoNing Province, China ; China Scholarship Council ; FCT/MCTES (PIDDAC) ; 2DMAT4FUEL (COMPETE2020 - FCT/MCTES - PIDDAC, Portugal) |
| 源URL | [http://ir.imr.ac.cn/handle/321006/174983]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Li, Bo; Liu, Lifeng |
| 作者单位 | 1.Inst Politecn Porto, Inst Super Engn Porto, Ctr Innovat Engn & Ind Technol, P-4249015 Porto, Portugal 2.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Adv Spectra Electrochem & Li On Batteries, Dalian 116023, Peoples R China 3.Univ Politecn Valencia Consejo Super Invest Cient, Inst Tecnol Quim, Ave Naranjos S-N, Valencia 46022, Spain 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 5.Univ Porto, Fac Engn, ALiCE Associate Lab Chem Engn, Rua Dr Roberto Frias, P-4200165 Porto, Portugal 6.Univ Porto, Fac Engn, LSRE LCM Lab Separat & React Engn, Lab Catalysis & Mat, Rua Dr Roberto Frias, P-4200465 Porto, Portugal 7.Int Iberian Nanotechnol Lab INL, Clean Energy Cluster, Ave Mestre Jose Veiga, P-4715330 Braga, Portugal |
| 推荐引用方式 GB/T 7714 | Yu, Zhipeng,Si, Chaowei,Javier Escobar-Bedia, Francisco,et al. Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis[J]. INORGANIC CHEMISTRY FRONTIERS,2022:9. |
| APA | Yu, Zhipeng.,Si, Chaowei.,Javier Escobar-Bedia, Francisco.,LaGrow, Alec P..,Xu, Junyuan.,...&Liu, Lifeng.(2022).Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis.INORGANIC CHEMISTRY FRONTIERS,9. |
| MLA | Yu, Zhipeng,et al."Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis".INORGANIC CHEMISTRY FRONTIERS (2022):9. |
入库方式： OAI收割
来源：金属研究所
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