Flexible high-energy and stable rechargeable vanadium-zinc battery based on oxygen defect modulated V2O5 cathode
文献类型：期刊论文
| 作者 | Liang, Xinyue; Yan, Lijin; Li, Wenpo; Bai, Youcun; Zhu, Chong; Qiang, Yujie; Xiong, Bingxue; Xiang, Bin; Zou, Xuefeng |
| 刊名 | NANO ENERGY
 |
| 出版日期 | 2021 |
| 卷号 | 87 |
| 关键词 | HIGH-PERFORMANCE ION BATTERY HIGH-POWER CAPACITANCE ELECTRODES INTERCALATION CONSTRUCTION MICROSPHERES DENSITIES STORAGE |
| 英文摘要 | The development of earth-abundant, high-capacity and stable cathode materials for robust aqueous Zn-ion batteries (ZIBs) is an ongoing challenge. With the merits of suitable operating voltage window and highly reversible redox reaction, vanadium oxide has recently emerged as an attractive cathode material. Herein, an oxygen defect modulated binder-free V2O5 nanorods (named as PVO@C) was constructed for aqueous/quasi-solid-state Zn ion battery. Accompanying the fast electron transport ability, increased concentration of oxygen defect and enhanced active sites, the aqueous PVO@C//Zn battery delivers an excellent high capacity of 385.34 mAh g(-1) at 0.13 A g(-1) and robust long-term life span of 86.7% capacity retention after 5000 cycles with nearly 100% coulomb efficiency. In particular, the assembled quasi-solid-state ZIBs exhibited the high voltage of 1.3 V, yielding an admirable energy density of 10.5 mWh cm(3) at a power density of 33.4 mW cm(3) and admirable cycling performance. What's more, the solid-state ZIB exhibits extremely high safety, wettability and wear-ability over the lithium ion batteries. It performs well even at a variety of severe hazardous conditions, such as punctured, soaked, bent, sewed, washed, cut, and hammered conditions. This work innovatively proposes the synergistic effect of oxygen defect modulation and phosphorus doping to optimize reaction kinetics, which will lead to further improvements in the performance of metal oxides electrode. This strategy can be extended to electrode materials of other battery systems for the construction of highly efficient flexible energy storage devices and accelerated the commercialization of wearable electronics technology. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21622]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | Xiang, B (corresponding author), Chongqing Univ, Sch Chem & Chem Engn, Chongqing 401331, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Liang, Xinyue,Yan, Lijin,Li, Wenpo,et al. Flexible high-energy and stable rechargeable vanadium-zinc battery based on oxygen defect modulated V2O5 cathode[J]. NANO ENERGY,2021,87. |
| APA | Liang, Xinyue.,Yan, Lijin.,Li, Wenpo.,Bai, Youcun.,Zhu, Chong.,...&Zou, Xuefeng.(2021).Flexible high-energy and stable rechargeable vanadium-zinc battery based on oxygen defect modulated V2O5 cathode.NANO ENERGY,87. |
| MLA | Liang, Xinyue,et al."Flexible high-energy and stable rechargeable vanadium-zinc battery based on oxygen defect modulated V2O5 cathode".NANO ENERGY 87(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。