Super-anticorrosive inverse nacre-like graphene-epoxy composite coating
文献类型:期刊论文
作者 | Ding, Jiheng; Zhao, Hongran; Zhou, Min; Liu, Panlin; Yu, Haibin |
刊名 | CARBON
![]() |
出版日期 | 2021 |
卷号 | 181页码:204-211 |
关键词 | SILANE COUPLING AGENTS CORROSION PROTECTION HYBRID COATINGS OXIDE PERFORMANCE CONDUCTIVITY POLYANILINE IMPROVEMENT INHIBITION MATRIX |
英文摘要 | Graphene-based coatings (GCs) have emerged as attractive candidates for engineering applications. Despite recent progresses, efforts to achieve high-performance and durable GCs through conventional blending have been frustrated due to the uncontrolled distribution and orientation of graphene nanosheets, which degrades anticorrosion properties. By mimicking the nacre's microstructure, here we successfully fabricated a bioinspired GC, in which graphene nanosheets self-assembly in smectic can order in the epoxy matrix. As the bioinspired coating (similar to 98 wt% of epoxy polymer) shows an inverse composition to nacre (similar to 96 wt% of aragonite nanoplatelets), thus which is called an ``inverse nacre-like'' coating. The resultant bioinspired coating has high compactness and alignment degree, resulting in greatly enhanced physical barrier property and anticorrosion performance. Electrochemical tests reveal that the impedance modulus is 3 orders of magnitude much higher than that of blank coating. More importantly, the bioinspired coating shows a highly anisotropic conductivity due to the anisotropic graphene layers, preventing local galvanic corrosion through eliminating the current leakage in the outof-plane direction. (C) 2021 Elsevier Ltd. All rights reserved. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21632] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | Ding, JH (corresponding author), Chinese Acad Sci, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Ding, Jiheng,Zhao, Hongran,Zhou, Min,et al. Super-anticorrosive inverse nacre-like graphene-epoxy composite coating[J]. CARBON,2021,181:204-211. |
APA | Ding, Jiheng,Zhao, Hongran,Zhou, Min,Liu, Panlin,&Yu, Haibin.(2021).Super-anticorrosive inverse nacre-like graphene-epoxy composite coating.CARBON,181,204-211. |
MLA | Ding, Jiheng,et al."Super-anticorrosive inverse nacre-like graphene-epoxy composite coating".CARBON 181(2021):204-211. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。