La(CH2C6H4NMe2-o)(3)-catalyzed reduction of esters to alcohols with pinacolborane
文献类型:期刊论文
作者 | Zhang, Fangcao; Gong, Mingliang; Xie, Hongzhen; Luo, Yunjie |
刊名 | NEW JOURNAL OF CHEMISTRY
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出版日期 | 2021 |
卷号 | 45期号:37页码:17654-17659 |
关键词 | MAGNESIUM-CATALYZED HYDROBORATION HYDROGENATION COMPLEXES |
英文摘要 | Catalytic reduction of esters is a favourable synthetic strategy to obtain the corresponding alcohols. La(CH2C6H4NMe2-o)(3), a simple and facilely accessible lanthanide complex, can serve as a highly efficient catalyst for the reduction of esters with pinacolborane (HBpin), selectively affording alcohols in good yields under mild conditions. This protocol exhibits good tolerance for many functional groups such as C=C double bond, nitro, halogen, furyl, and thienyl groups. A lanthanum hydride species like [La]-H center dot HBpin is supposed to play a crucial role in promoting the interaction of esters with HBpin. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21642] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | 1.Xie, HZ 2.Luo, YJ (corresponding author), Key Lab Adv Mass Spectrometry & Mol Anal Zhejiang, Ningbo 315211, Peoples R China. 3.Luo, YJ (corresponding author), Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China. |
推荐引用方式 GB/T 7714 | Zhang, Fangcao,Gong, Mingliang,Xie, Hongzhen,et al. La(CH2C6H4NMe2-o)(3)-catalyzed reduction of esters to alcohols with pinacolborane[J]. NEW JOURNAL OF CHEMISTRY,2021,45(37):17654-17659. |
APA | Zhang, Fangcao,Gong, Mingliang,Xie, Hongzhen,&Luo, Yunjie.(2021).La(CH2C6H4NMe2-o)(3)-catalyzed reduction of esters to alcohols with pinacolborane.NEW JOURNAL OF CHEMISTRY,45(37),17654-17659. |
MLA | Zhang, Fangcao,et al."La(CH2C6H4NMe2-o)(3)-catalyzed reduction of esters to alcohols with pinacolborane".NEW JOURNAL OF CHEMISTRY 45.37(2021):17654-17659. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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