Insight into the Active Site in Electrochemical CO2 Reduction of Self-Supported Cobalt Phthalocyanine Anchored on ZnIn2S4 Nanoarrays
文献类型:期刊论文
作者 | Zhu, Hong-Lin; Liu, Lin-Chang; Li, Zhong-Yi; Ma, Jing-Jing; Zheng, Yue-Qing; Shui, Miao |
刊名 | ACS APPLIED ENERGY MATERIALS
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出版日期 | 2021 |
卷号 | 4期号:7页码:6616-6623 |
关键词 | ELECTROREDUCTION PORPHYRIN |
英文摘要 | Electrocatalytic CO2 reduction into value-added fuels is a promising and economical strategy to mitigate CO2 emissions. Herein, a self-supported cobalt phthalocyanine anchored on chrysanthemum-like ZnIn2S4 nanoarray electrode was prepared. By integration of experimental analysis and density functional theory calculation, the CoPc molecule was anchored with hexagonal ZnIn2S4 (ZIS) via S-C and Co-S interaction. The active site for CO2RR in ZIS-CoPc was attributed to Co sites. For hydrogen evolution reaction, the active site was mainly ascribed to the S site on the surface of ZIS. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21710] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | 1.Zheng, YQ 2.Shui, M (corresponding author), Ningbo Univ, Chem Inst Synth & Green Applicat, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China. 3.Shui, M (corresponding author), Ningbo Univ, Sch Microelect Sci & Engn, Ningbo 315211, Peoples R China. |
推荐引用方式 GB/T 7714 | Zhu, Hong-Lin,Liu, Lin-Chang,Li, Zhong-Yi,et al. Insight into the Active Site in Electrochemical CO2 Reduction of Self-Supported Cobalt Phthalocyanine Anchored on ZnIn2S4 Nanoarrays[J]. ACS APPLIED ENERGY MATERIALS,2021,4(7):6616-6623. |
APA | Zhu, Hong-Lin,Liu, Lin-Chang,Li, Zhong-Yi,Ma, Jing-Jing,Zheng, Yue-Qing,&Shui, Miao.(2021).Insight into the Active Site in Electrochemical CO2 Reduction of Self-Supported Cobalt Phthalocyanine Anchored on ZnIn2S4 Nanoarrays.ACS APPLIED ENERGY MATERIALS,4(7),6616-6623. |
MLA | Zhu, Hong-Lin,et al."Insight into the Active Site in Electrochemical CO2 Reduction of Self-Supported Cobalt Phthalocyanine Anchored on ZnIn2S4 Nanoarrays".ACS APPLIED ENERGY MATERIALS 4.7(2021):6616-6623. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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