中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride)

文献类型:期刊论文

作者Hao, Yanying; Wang, Guyue; Shui, Xiaoxue; Tian, Anping; Yang, Yong; Zhu, Jin
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2021
卷号138期号:47
关键词BIO-BASED PLASTICIZERS WASTE COOKING OIL DIALKYL FURAN-2,5-DICARBOXYLATES MECHANICAL-PROPERTIES ACID SYNTHESIS PVC ESTERS CARDANOL
英文摘要A series of bio-based diester plasticizers with various alkyl chain asymmetry and the same molecular weight were designed and synthesized, using renewable 5-hydroxymethyl-2-furancarboxylic acid (HFCA) as the raw material. The chemical structures of the HFCA-based plasticizers were characterized by Fourier transform infrared and nuclear magnetic resonance (H-1 NMR and C-13 NMR). Besides, the influence of alkyl chain asymmetry on plasticization properties of the HFCA-based plasticizers in poly(vinyl chloride) (PVC) blends was also investigated. It was found that increasing the alkyl chain asymmetry of the diester plasticizer and keeping the molecular weight unchanged simultaneously could further improve its plasticizing efficiency, without sacrificing its volatility resistance and exudation resistance. The results showed that this study provided a new approach for further optimizing the overall properties of the asymmetric diester plasticizers.
源URL[http://ir.nimte.ac.cn/handle/174433/21727]  
专题中国科学院宁波材料技术与工程研究所
2021专题_期刊论文
作者单位1.Yang, Y
2.Zhu, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Peoples R China.
推荐引用方式
GB/T 7714
Hao, Yanying,Wang, Guyue,Shui, Xiaoxue,et al. Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride)[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2021,138(47).
APA Hao, Yanying,Wang, Guyue,Shui, Xiaoxue,Tian, Anping,Yang, Yong,&Zhu, Jin.(2021).Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride).JOURNAL OF APPLIED POLYMER SCIENCE,138(47).
MLA Hao, Yanying,et al."Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride)".JOURNAL OF APPLIED POLYMER SCIENCE 138.47(2021).

入库方式: OAI收割

来源:宁波材料技术与工程研究所

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