Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride)
文献类型:期刊论文
作者 | Hao, Yanying; Wang, Guyue; Shui, Xiaoxue; Tian, Anping; Yang, Yong; Zhu, Jin |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2021 |
卷号 | 138期号:47 |
关键词 | BIO-BASED PLASTICIZERS WASTE COOKING OIL DIALKYL FURAN-2,5-DICARBOXYLATES MECHANICAL-PROPERTIES ACID SYNTHESIS PVC ESTERS CARDANOL |
英文摘要 | A series of bio-based diester plasticizers with various alkyl chain asymmetry and the same molecular weight were designed and synthesized, using renewable 5-hydroxymethyl-2-furancarboxylic acid (HFCA) as the raw material. The chemical structures of the HFCA-based plasticizers were characterized by Fourier transform infrared and nuclear magnetic resonance (H-1 NMR and C-13 NMR). Besides, the influence of alkyl chain asymmetry on plasticization properties of the HFCA-based plasticizers in poly(vinyl chloride) (PVC) blends was also investigated. It was found that increasing the alkyl chain asymmetry of the diester plasticizer and keeping the molecular weight unchanged simultaneously could further improve its plasticizing efficiency, without sacrificing its volatility resistance and exudation resistance. The results showed that this study provided a new approach for further optimizing the overall properties of the asymmetric diester plasticizers. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21727] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | 1.Yang, Y 2.Zhu, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Hao, Yanying,Wang, Guyue,Shui, Xiaoxue,et al. Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride)[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2021,138(47). |
APA | Hao, Yanying,Wang, Guyue,Shui, Xiaoxue,Tian, Anping,Yang, Yong,&Zhu, Jin.(2021).Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride).JOURNAL OF APPLIED POLYMER SCIENCE,138(47). |
MLA | Hao, Yanying,et al."Design and synthesis of HFCA-based plasticizers with asymmetrical alkyl chains for poly(vinyl chloride)".JOURNAL OF APPLIED POLYMER SCIENCE 138.47(2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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