Ultrafast and high-efficient self-healing epoxy coatings with active multiple hydrogen bonds for corrosion protection
文献类型:期刊论文
作者 | Liu, Tong; Zhao, Haichao; Zhang, Dawei; Lou, Yuntian; Huang, Luyao; Ma, Lingwei; Hao, Xiangping; Dong, Liang; Rosei, Federico; Lau, Woon Ming |
刊名 | CORROSION SCIENCE
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出版日期 | 2021 |
卷号 | 187 |
关键词 | ATMOSPHERIC CORROSION MECHANICAL-PROPERTIES TEMPERATURE PERFORMANCE POLYMERS COMBINATION RESISTANCE NETWORKS BEHAVIOR EIS |
英文摘要 | Combining a fast self-healing action and a high barrier property remains a challenge in polymeric protective coatings. Herein, we report an intrinsic self-healing epoxy coating in which 2-ureido-4[1H]-pyrimidinone (UPy) as a quadruple hydrogen bonding unit, grafted onto the backbones of an epoxy-matrix by an amine-terminated oligo(propylene glycol) linker. Without any intervention, the epoxy-matrix performs its self-healing function in similar to 5 min, even under aqueous immersion. Besides, electrochemical impedance spectroscopy measurements demonstrate corrosion protection ability of such self-healed coating on a steel substrate, with a high vertical bar Z vertical bar(0.01Hz) value of 4.8 x 10(10) Omega.cm(2) after 60 days of immersion in NaCl solution. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21744] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | 1.Hao, XP (corresponding author), Univ Sci & Technol Beijing, Natl Mat Corros & Protect Data Ctr, Beijing 100083, Peoples R China. 2.Zhang, DW |
推荐引用方式 GB/T 7714 | Liu, Tong,Zhao, Haichao,Zhang, Dawei,et al. Ultrafast and high-efficient self-healing epoxy coatings with active multiple hydrogen bonds for corrosion protection[J]. CORROSION SCIENCE,2021,187. |
APA | Liu, Tong.,Zhao, Haichao.,Zhang, Dawei.,Lou, Yuntian.,Huang, Luyao.,...&Lau, Woon Ming.(2021).Ultrafast and high-efficient self-healing epoxy coatings with active multiple hydrogen bonds for corrosion protection.CORROSION SCIENCE,187. |
MLA | Liu, Tong,et al."Ultrafast and high-efficient self-healing epoxy coatings with active multiple hydrogen bonds for corrosion protection".CORROSION SCIENCE 187(2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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