Ni3N-V2O3 enables highly efficient 5-(Hydroxymethyl) furfural oxidation enabling membrane free hydrogen production
文献类型：期刊论文
| 作者 | Liang, Shuqin; Pan, Longhai; Thomas, Tiju; Zhu, Bin; Chen, Chunlin; Zhang, Jian; Shen, Hangjia; Liu, Jian; Yang, Minghui |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2021 |
| 卷号 | 415 |
| 关键词 | WATER BIOMASS GENERATION CONVERSION NANOSHEETS EVOLUTION NANOARRAY CATALYSTS DESIGN |
| 英文摘要 | Conventional water electrolyzers produce H-2 and O-2 simultaneously. The sluggish water oxidation reaction (WOR) results in low overall energy conversion efficiency; also the production of O-2 is not of economic value. Thus, replacing sluggish anodic water oxidation reaction with 5-(Hydroxymethyl) furfural oxidation reaction (HmfOR) has been considered as a more energy-efficient strategy to produce hydrogen. Here, Ni3N incorporated by V2O3 is synthesized via thermal ammonolysis, which shows excellent bifunctional electrocatalytic performance for hydrogen evolution reaction (HER) and HmfOR. The electrocatalyst has strong tolerance to Hmf, which avoids the use of membrane. The Ni3N-V2O3 hybrids shows a low overpotential of 53 mV for HER, and a low overpotential of 230 mV for HmfOR, which is below 140 mV for WOR at 10 mA cm(-2). When Ni3N-V2O3 is employed as a bifunctional electrode, it offers a cell voltage of only 1.40 V at 10 mA cm(-2) for continuously hydrogen production. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21768]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Liu, J 2.Liu, J (corresponding author), China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China. 3.Liu, J (corresponding author), China Univ Petr, Beijing Key Lab Oil & Gas Pollut Control, Beijing 102249, Peoples R China. 4.Shen, HJ 5.Yang, MH (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Liang, Shuqin,Pan, Longhai,Thomas, Tiju,et al. Ni3N-V2O3 enables highly efficient 5-(Hydroxymethyl) furfural oxidation enabling membrane free hydrogen production[J]. CHEMICAL ENGINEERING JOURNAL,2021,415. |
| APA | Liang, Shuqin.,Pan, Longhai.,Thomas, Tiju.,Zhu, Bin.,Chen, Chunlin.,...&Yang, Minghui.(2021).Ni3N-V2O3 enables highly efficient 5-(Hydroxymethyl) furfural oxidation enabling membrane free hydrogen production.CHEMICAL ENGINEERING JOURNAL,415. |
| MLA | Liang, Shuqin,et al."Ni3N-V2O3 enables highly efficient 5-(Hydroxymethyl) furfural oxidation enabling membrane free hydrogen production".CHEMICAL ENGINEERING JOURNAL 415(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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