Confined Channels Induced Coalescence Demulsification and Slippery Interfaces Constructed Fouling Resist-Release for Long-Lasting Oil/Water Separation
文献类型:期刊论文
作者 | Ding, Yajie; Hu, Bihan; Zhuang, Liwei; Wang, Jianqiang; Wu, Jindan; Liu, Fu; Wang, Jiping |
刊名 | ACS APPLIED MATERIALS & INTERFACES
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出版日期 | 2021 |
卷号 | 13期号:25页码:30224-30234 |
关键词 | IN-OIL EMULSIONS POLY(VINYLIDENE FLUORIDE) MEMBRANES NANOFIBER MEMBRANES INORGANIC MEMBRANES JANUS MEMBRANES PVDF MEMBRANES CRUDE-OIL WATER PERFORMANCE SUPEROLEOPHOBICITY |
英文摘要 | Superwetting membranes based on steric exclusion and affinity difference have drawn substantial interest for oil/water separation. However, the state-of-the-art membranes fail to literally sort out fouling and permeability decline and so limit their viability for long-term separation. Inspired by Dayu's philosophy of draining rather than blocking water, herein, we achieve a long-lasting and efficient separation for viscous emulsions by designing poly(hydroxyethyl methylacrylate) (PHEMA)- and polydimethylsiloxane (PDMS)-compensated poly(vinylidene fluoride) membranes based on coalescence demulsification via chemical coordination phase separation. The symmetric and torturous microporous structure facilitated oil spatial confining and coalescence demulsification, while the synergistic compensation of PHEMA and PDMS coordinated the fouling resist and release properties, which was confirmed by multichannel confocal laser scanning microscopy. The developed membrane shows an unprecedented permeability half-life (t) for viscous emulsions (e.g., decamethylcyclopentasiloxane, soybean oil paraffin, n-hexadecane, and isooctane) under cross-flow operation, far more beyond common superwetting membranes under applied bench-scale dead-end filtration. Our technique for designing nonfouling membranes opens up opportunities for advancing next-generation membranes for oil/water separation. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21806] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | 1.Liu, F (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China. 2.Wang, JQ 3.Liu, F (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Ding, Yajie,Hu, Bihan,Zhuang, Liwei,et al. Confined Channels Induced Coalescence Demulsification and Slippery Interfaces Constructed Fouling Resist-Release for Long-Lasting Oil/Water Separation[J]. ACS APPLIED MATERIALS & INTERFACES,2021,13(25):30224-30234. |
APA | Ding, Yajie.,Hu, Bihan.,Zhuang, Liwei.,Wang, Jianqiang.,Wu, Jindan.,...&Wang, Jiping.(2021).Confined Channels Induced Coalescence Demulsification and Slippery Interfaces Constructed Fouling Resist-Release for Long-Lasting Oil/Water Separation.ACS APPLIED MATERIALS & INTERFACES,13(25),30224-30234. |
MLA | Ding, Yajie,et al."Confined Channels Induced Coalescence Demulsification and Slippery Interfaces Constructed Fouling Resist-Release for Long-Lasting Oil/Water Separation".ACS APPLIED MATERIALS & INTERFACES 13.25(2021):30224-30234. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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