Thermodynamic re-assessment and liquidus projection of the Cu-Ni-Ti system
文献类型:期刊论文
作者 | Jin, Bo; Lu, Xingxu; Liu, Shuhong; Xu, Kai; Du, Yong; Zhang, Shuyan; Chu, Mingqiang |
刊名 | CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
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出版日期 | 2021 |
卷号 | 73 |
关键词 | COUPLED PHASE-DIAGRAMS TITANIUM-NICKEL SYSTEM GLASS-FORMING ABILITY BULK METALLIC GLASSES RICH REGION INTERMETALLIC COMPOUNDS THERMOCHEMICAL DATA X-RAY EQUILIBRIA TRANSITION |
英文摘要 | A critical thermodynamic re-assessment for the ternary Cu-Ni-Ti system was performed by means of the CALPHAD (CALculation of PHAse Diagram) approach, and a new set of self-consistent thermodynamic parameters for the Cu-Ni-Ti system was obtained. According to the reported crystal structures and homogeneity ranges, appropriate sublattice models were proposed for the tau 4 and tau 6 phases, which could achieve a better description than the previous stoichiometric compound model for phase compositions and primary phase regions. Three solid-state invariant reactions, CuTi + tau 1 <-> Cu4Ti3 + NiTi at 1074.86 K, Ni3Ti + NiTi + tau 1 <-> tau 2 at 1074.39 K and NiTi + tau 4 <-> Ni3Ti + tau 1 at 1175.11 K were predicted in the present work. Presently calculated liquidus projection eliminated the liquid miscibility gap of the Cu-Ni-Ti system on Cu-Ni side. Scheil reaction scheme of the entire composition range was also presented accordingly. Comparisons between the calculated results and the measured phase equilibria indicated that all the reliable experimental data were satisfactorily accounted for by the present modeling. |
源URL | [http://ir.nimte.ac.cn/handle/174433/21872] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | Liu, SH (corresponding author), Cent South Univ, Natl Key Lab Sci & Technol Natl Def High Strength, Changsha 410083, Hunan, Peoples R China. |
推荐引用方式 GB/T 7714 | Jin, Bo,Lu, Xingxu,Liu, Shuhong,et al. Thermodynamic re-assessment and liquidus projection of the Cu-Ni-Ti system[J]. CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY,2021,73. |
APA | Jin, Bo.,Lu, Xingxu.,Liu, Shuhong.,Xu, Kai.,Du, Yong.,...&Chu, Mingqiang.(2021).Thermodynamic re-assessment and liquidus projection of the Cu-Ni-Ti system.CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY,73. |
MLA | Jin, Bo,et al."Thermodynamic re-assessment and liquidus projection of the Cu-Ni-Ti system".CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY 73(2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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