Direct Conversion of 5-Hydroxymethylfurfural to Furanic Diether by Copper-Loaded Hierarchically Structured ZSM-5 Catalyst in a Fixed-Bed Reactor
文献类型：期刊论文
| 作者 | Hu, Hualei; Xue, Tingting; Zhang, Zhenxin; Gan, Jiang; Chen, Liangqi; Zhang, Jian; Qu, Fengzuo; Cai, Weijie; Wang, Lei |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2021 |
| 卷号 | 13期号:15页码:3461-3469 |
| 关键词 | TRANSFER HYDROGENATION REDUCTIVE ETHERIFICATION SELECTIVE HYDROGENATION CU/AL2O3 CATALYSTS EFFICIENT ZEOLITE ACID LEWIS 2,5-BIS(HYDROXYMETHYL)FURAN PERFORMANCE |
| 英文摘要 | The highly-efficient conversion of 5-hydroxymethylfurfural (HMF) to 2,5-bis(ethoxymethyl)furan (BEMF) was achieved over the copper-loaded hierarchically structured ZSM-5 (Cu/HSZ) catalysts in the continuous fixed-bed reactor. The main reaction path for BEMF synthesis on the Cu/HSZ catalysts was confirmed as following: HMF was firstly hydrogenated to BHMF intermediates over metal sites and then the formed BHMF was etherified by acid sites. Benefiting from the ammonia evaporation (AE) method promoted the dispersion of copper and reduced the acidity, the Cu/HSZ-AE catalyst exhibited more excellent BEMF yield and stability than the catalyst prepared by conventional incipient-wetness impregnation (Cu/HSZ-IW). Indeed, the inactivation of Cu/HSZ-IW catalyst was mainly attributed to the deactivation of copper by carbon species deposition. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21887]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Wang, L (corresponding author), Zhejiang Sugar Energy Technol Co Ltd, 1818 Zhongguan West Rd, Ningbo 315201, Peoples R China. 2.Zhang, J 3.Wang, L (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, 1219 Zhongguan West Rd, Ningbo 315201, Peoples R China. 4.Cai, WJ (corresponding author), Dalian Polytech Univ, 1st Qinggongyuan, Dalian 116034, Peoples R China. 5.Zhang, J (corresponding author), Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Hu, Hualei,Xue, Tingting,Zhang, Zhenxin,et al. Direct Conversion of 5-Hydroxymethylfurfural to Furanic Diether by Copper-Loaded Hierarchically Structured ZSM-5 Catalyst in a Fixed-Bed Reactor[J]. CHEMCATCHEM,2021,13(15):3461-3469. |
| APA | Hu, Hualei.,Xue, Tingting.,Zhang, Zhenxin.,Gan, Jiang.,Chen, Liangqi.,...&Wang, Lei.(2021).Direct Conversion of 5-Hydroxymethylfurfural to Furanic Diether by Copper-Loaded Hierarchically Structured ZSM-5 Catalyst in a Fixed-Bed Reactor.CHEMCATCHEM,13(15),3461-3469. |
| MLA | Hu, Hualei,et al."Direct Conversion of 5-Hydroxymethylfurfural to Furanic Diether by Copper-Loaded Hierarchically Structured ZSM-5 Catalyst in a Fixed-Bed Reactor".CHEMCATCHEM 13.15(2021):3461-3469. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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