Recent advances on electrocatalytic fixation of nitrogen under ambient conditions
文献类型：期刊论文
| 作者 | Wu, Bin; Lin, Yichao; Wang, Xuezhen; Chen, Liang |
| 刊名 | MATERIALS CHEMISTRY FRONTIERS
 |
| 出版日期 | 2021 |
| 卷号 | 5期号:15页码:5516-5533 |
| 关键词 | ELECTROCHEMICAL AMMONIA-SYNTHESIS ARTIFICIAL N-2 FIXATION REDUCTION REACTION EFFICIENT ELECTROCATALYST BISMUTH NANOSHEETS RECENT PROGRESS DOPED GRAPHENE DINITROGEN ELECTROREDUCTION OXIDE |
| 英文摘要 | As one of the most important chemicals for human beings, ammonia is produced by the well-known Haber-Bosch process, which consumes tremendous amounts of energy and simultaneously results in unwanted emissions. Very recently, the electrochemical nitrogen reduction reaction (e-NRR) emerged as an intriguing technique for nitrogen fixation, which can be driven by sustainable power sources, such as solar and wind energy. Moreover, ammonia produced by e-NRR can be realized under mild conditions. Nevertheless, the electrochemical nitrogen fixation suffers from a low yield of ammonia due to the scaling relations of intermediates and competing hydrogen evolution. In addition, the progress in the e-NRR is also hindered by unreliable ammonia measurements. In this review, we summarize and discuss the recently reported e-NRR electrocatalysts, and highlight the e-NRR mechanisms and promising strategies for the rational design of e-NRR electrocatalysts. Importantly, the nitrogen contaminations, which resulted in false positive results, are also mentioned and a rigorous ammonia detection method is presented. Moreover, the current challenges and prospects for e-NRR catalysis are discussed. This review gives a fresh impetus to the rational design of high-performance e-NRR electrocatalysts. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21895]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Chen, L (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China. 2.Lin, YC 3.Wang, XZ 4.Chen, L (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wu, Bin,Lin, Yichao,Wang, Xuezhen,et al. Recent advances on electrocatalytic fixation of nitrogen under ambient conditions[J]. MATERIALS CHEMISTRY FRONTIERS,2021,5(15):5516-5533. |
| APA | Wu, Bin,Lin, Yichao,Wang, Xuezhen,&Chen, Liang.(2021).Recent advances on electrocatalytic fixation of nitrogen under ambient conditions.MATERIALS CHEMISTRY FRONTIERS,5(15),5516-5533. |
| MLA | Wu, Bin,et al."Recent advances on electrocatalytic fixation of nitrogen under ambient conditions".MATERIALS CHEMISTRY FRONTIERS 5.15(2021):5516-5533. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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