Fast and Stable Electrochemical Production of H2O2 by Electrode Architecture Engineering
文献类型：期刊论文
| 作者 | Xu, Wenwen; Liang, Zheng; Gong, Shun; Zhang, Baoshan; Wang, Hui; Su, Linfeng; Chen, Xu; Han, Nana; Tian, Ziqi; Kallio, Tanja |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2021 |
| 卷号 | 9期号:20页码:7120-7129 |
| 关键词 | ADVANCED OXIDATION PROCESSES HYDROGEN-PEROXIDE OXYGEN REDUCTION TRANSITION-METAL FENTON CATALYSTS SURFACES WATER ELECTROSYNTHESIS NANOCRYSTALS |
| 英文摘要 | Fast and stable production of hydrogen peroxide (H2O2) through electrochemical pathways is crucial for wastewater treatment applications. With this objective, herein, we report an integrated and superaerophilic electrode composed of atomically dispersed Ni-O-C site-enriched carbon nanosheets (IS-NiOC electrode) for electrochemical oxygen reduction to produce H2O2. Both experimental and theoretical results have proven that atomically dispersed Ni-O-C sites enable a low overpotential (260 mV at 0.1 mA cm(-2)) and high selectivity (>90% at 0.0-0.5 V vs reversible hydrogen electrode (RHE)) in a neutral electrolyte. Compared with a commercial gas-diffusion electrode, the IS-NiOC electrode offers stronger affinity to oxygen bubbles and more robust three-phase contact points, resulting in high current density (similar to 106 mA cm(-2) at 0.25 V vs RHE) and superior stability (similar to 200 h). These merits allow the application of the IS-NiOC electrode in an electro-Fenton-like process, which enables fast degradation of representative organic pollutants in both a steady state and a flow state. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21901]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Lu, ZY (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China. 2.Chen, L 3.Lu, ZY (corresponding author), Chinese Acad Sci, Inst New Energy Technol, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Xu, Wenwen,Liang, Zheng,Gong, Shun,et al. Fast and Stable Electrochemical Production of H2O2 by Electrode Architecture Engineering[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(20):7120-7129. |
| APA | Xu, Wenwen.,Liang, Zheng.,Gong, Shun.,Zhang, Baoshan.,Wang, Hui.,...&Sun, Xiaoming.(2021).Fast and Stable Electrochemical Production of H2O2 by Electrode Architecture Engineering.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(20),7120-7129. |
| MLA | Xu, Wenwen,et al."Fast and Stable Electrochemical Production of H2O2 by Electrode Architecture Engineering".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.20(2021):7120-7129. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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