Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)(2)](2)(THF)(2)
文献类型：期刊论文
| 作者 | Yu, Chong; Guo, Chenjun; Jiang, Linhong; Gong, Mingliang; Luo, Yunjie |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2021 |
| 卷号 | 40期号:9页码:1201-1206 |
| 关键词 | CHEMOSELECTIVE REDUCTION HYDROBORATION REDUCTION ALCOHOL AMINATION MILD REDUCTION MAGNESIUM ALDEHYDES BIS(TRIMETHYLSILYL)AMIDES HYDROAMINATION HYDROGENATION COMPLEXES |
| 英文摘要 | Deoxygenative reduction of amides is a challenging but favorable synthetic method of accessing amines. In the presence of a catalytic amount of Ca[N(SiMe3)(2)](2)(THF)(2), pinacolborane (HBpin) could efficiently reduce a broad scope of amides, primary amides in particular, into corresponding amines. Functional groups and heteroatoms showed good tolerance in this process of transformation, and a plausible reaction mechanism was proposed. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21933]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Luo, YJ (corresponding author), Key Lab Adv Mass Spectrometry & Mol Anal Zhejiang, Ningbo 315211, Peoples R China. 2.Luo, YJ (corresponding author), Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Yu, Chong,Guo, Chenjun,Jiang, Linhong,et al. Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)(2)](2)(THF)(2)[J]. ORGANOMETALLICS,2021,40(9):1201-1206. |
| APA | Yu, Chong,Guo, Chenjun,Jiang, Linhong,Gong, Mingliang,&Luo, Yunjie.(2021).Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)(2)](2)(THF)(2).ORGANOMETALLICS,40(9),1201-1206. |
| MLA | Yu, Chong,et al."Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)(2)](2)(THF)(2)".ORGANOMETALLICS 40.9(2021):1201-1206. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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