Towards superior nickel oxide electrochromic films using Si and Li co-doping and rapid thermal annealing
文献类型：期刊论文
| 作者 | Wu, Chao; Yang, Ye; Feng, Wangwang; Song, Weijie; Tan, Ruiqin |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
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| 出版日期 | 2021 |
| 卷号 | 862 |
| 英文摘要 | Herein, we firstly report a novel technical routine to improve the electrochromic (EC) performance of frequently-used nickel oxide counter-electrode films by RF magnetron sputtering using a Si and Li co-doping oxide target in Ar atmosphere and subsequently rapid thermal annealing (RTA) at 400 degrees C in air. The effects of co-doping and RTA treatment on the phase structure, microstructure, chemical states of Ni element, and EC properties of films were comprehensively investigated using X-ray diffraction, scanning electron microscope, X-ray photoelectron spectroscopy and electrochemical analysis. Comparing with the undoped and the as-deposited films, it is found that the mutual effects of Si and Li co-doping and RTA treatment can promote a preferential growth in (111) direction of nickel oxide, enhance the relative atomic concentration of Ni3+ to 60% in the total Ni element, and help to form a smooth and compact structure with uniformly distributed fine pinholes. The doped and annealed film behaves with the highest bleached transmittance of 93.3% (at 550 nm), largest optical modulation of 37.0% (at 550 nm), biggest charge capacity of 14.8 mC.cm(-2), best electrochemical stability to bear more than 100 cycles, and rapid bleaching and coloring response times of 2.4 and 8.8 s. These superior performances make this kind of material promising for future application in high quality EC devices. (C) 2021 Elsevier B.V. All rights reserved. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21945]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Yang, Y (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 2.Tan, RQ (corresponding author), Ningbo Univ, Fac Elect Engn & Comp Sci, Ningbo 315211, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wu, Chao,Yang, Ye,Feng, Wangwang,et al. Towards superior nickel oxide electrochromic films using Si and Li co-doping and rapid thermal annealing[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2021,862. |
| APA | Wu, Chao,Yang, Ye,Feng, Wangwang,Song, Weijie,&Tan, Ruiqin.(2021).Towards superior nickel oxide electrochromic films using Si and Li co-doping and rapid thermal annealing.JOURNAL OF ALLOYS AND COMPOUNDS,862. |
| MLA | Wu, Chao,et al."Towards superior nickel oxide electrochromic films using Si and Li co-doping and rapid thermal annealing".JOURNAL OF ALLOYS AND COMPOUNDS 862(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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