Enhancing the stability of perovskite solar cells through cross-linkable and hydrogen bonding multifunctional additives
文献类型：期刊论文
| 作者 | Li, Xiaodong; Ke, Shanzhe; Feng, XiuXiu; Zhao, Xiaoyan; Zhang, Wenxiao; Fang, Junfeng |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2021 |
| 卷号 | 9期号:21页码:12684-12689 |
| 关键词 | LEAD IODIDE INDUCED DEGRADATION HIGH-EFFICIENCY ION-TRANSPORT PERFORMANCE LINKING DEFECTS |
| 英文摘要 | Ion migration, especially I- migration, is a main issue limiting the stability of perovskite solar cells (PSCs). Here, we introduce a multifunctional additive of dipentaerythritol pentaacrylate (DPPA) into perovskite films to suppress the ion migration. The CH2=CH groups in DPPA will crosslink at grain boundaries and block the channels of ion migration. Importantly, the alkoxy (-O-CH2) and hydroxyl (-OH) groups in DPPA can bond with the FA(+) and I- ions in the perovskite through hydrogen interaction, chemically immobilizing these migrated ions. As a result, ion migration in the perovskite is effectively inhibited owing to the synergistic function of DPPA. PSCs with DPPA exhibit a high efficiency of over 22% with good operational stability, retaining over 90% of maximum efficiency after maximum power point (MPP) tracking for 800 hours under continuous illumination. In addition, the air and thermal stabilities are also enhanced and over 90% of initial efficiency is retained after aging in air or at 85 degrees C for 1000 hours. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21947]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Fang, JF (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 2.Fang, JF (corresponding author), East China Normal Univ, Minist Educ, Sch Phys & Mat Sci, Nanophoton Adv Instrument Engn Res Ctr, Shanghai 200062, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Li, Xiaodong,Ke, Shanzhe,Feng, XiuXiu,et al. Enhancing the stability of perovskite solar cells through cross-linkable and hydrogen bonding multifunctional additives[J]. JOURNAL OF MATERIALS CHEMISTRY A,2021,9(21):12684-12689. |
| APA | Li, Xiaodong,Ke, Shanzhe,Feng, XiuXiu,Zhao, Xiaoyan,Zhang, Wenxiao,&Fang, Junfeng.(2021).Enhancing the stability of perovskite solar cells through cross-linkable and hydrogen bonding multifunctional additives.JOURNAL OF MATERIALS CHEMISTRY A,9(21),12684-12689. |
| MLA | Li, Xiaodong,et al."Enhancing the stability of perovskite solar cells through cross-linkable and hydrogen bonding multifunctional additives".JOURNAL OF MATERIALS CHEMISTRY A 9.21(2021):12684-12689. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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