Insight into bulk charge transfer of lithium metal anodes by synergism of nickel seeding and LiF-Li3N-Li2S co-doped interphase
文献类型：期刊论文
| 作者 | Li, Zhendong; Huai, Liyuan; Li, Shun; Ma, Mingming; Luo, Kailin; Zhao, Yang; Wang, Deyu; Sun, Xueliang; Peng, Zhe |
| 刊名 | ENERGY STORAGE MATERIALS
 |
| 出版日期 | 2021 |
| 卷号 | 37页码:491-500 |
| 英文摘要 | Cycling lithium (Li) metal anode with a low negative/positive capacity (N/P) ratio is critical to build high-energy-density Li metal batteries (LMBs). Many strategies focusing on interfacial protection are limited to shallow conditions using excessive Li with a high negative/positive capacity (N/P) ratio > 50. Herein, we demonstrate a deeply enhanced charge transfer kinetic by a rational incorporation of nickel (Ni) seeds in the Li anodes with a tailored interfacial chemistry. The Ni seeds in the bulk Li anode not only act as well-dispersed nucleation sites to enable Ni-seeded growth of granular Li deposits, but also adsorb acetonitrile (AN) molecules when the Ni-seeded Li anodes are paired with an AN-based electrolyte using lithium bis-(fluorosulfonyl)imide as salt, forming a fast Li+ conducing interphase with co-produced LiF, Li3N and Li2S components. These benefits conduct an exchange current density similar to 20 times higher than that of the bare Li in conventional carbonate electrolytes. Stable cycling of LMBs with a practical cathode loading (similar to 5 mAh cm(-2)) and a low N/P capacity ratio of 2 is also demonstrated, showing the prominence of this remedy for developing high-energy-density LMBs. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/21977]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Sun, XL (corresponding author), Univ Western Ontario, Dept Mech & Mat Engn, London, ON N6A 5B9, Canada. 2.Wang, DY (corresponding author), Tianmu Lake Inst Adv Energy Storage Technol, Liyang 213300, Peoples R China. 3.Wang, DY 4.Peng, Z (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 5.Wang, DY (corresponding author), Jianghan Univ, Sch Chem & Environm Engn, Key Lab Optoelect Chem Mat & Devices, Wuhan 430056, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Li, Zhendong,Huai, Liyuan,Li, Shun,et al. Insight into bulk charge transfer of lithium metal anodes by synergism of nickel seeding and LiF-Li3N-Li2S co-doped interphase[J]. ENERGY STORAGE MATERIALS,2021,37:491-500. |
| APA | Li, Zhendong.,Huai, Liyuan.,Li, Shun.,Ma, Mingming.,Luo, Kailin.,...&Peng, Zhe.(2021).Insight into bulk charge transfer of lithium metal anodes by synergism of nickel seeding and LiF-Li3N-Li2S co-doped interphase.ENERGY STORAGE MATERIALS,37,491-500. |
| MLA | Li, Zhendong,et al."Insight into bulk charge transfer of lithium metal anodes by synergism of nickel seeding and LiF-Li3N-Li2S co-doped interphase".ENERGY STORAGE MATERIALS 37(2021):491-500. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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