Bioinspired ultrathin graphene nanosheets sandwiched between epoxy layers for high performance of anticorrosion coatings
文献类型:期刊论文
作者 | Zhu, Xiaobo; Zhao, Haichao; Wang, Liping; Xue, Qunji |
刊名 | CHEMICAL ENGINEERING JOURNAL
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出版日期 | 2021 |
卷号 | 410 |
英文摘要 | The special brick-mud layered micro-nano structure of nacre has undergone millions of years of biological evolution, which can withstand the corrosion of seawater in different environments, and has both high strength and toughness. Inspired by mussels and natural nacre, we successfully designed a bionic epoxy-(graphene-dopamine)(n)-epoxy sandwich composite coating. Not only does dopamine act as a binder to improve the interfacial compatibility and adhesion between epoxy resin and graphene, but due to the hydrogen bonding and the electrostatic interaction of -COO - and -NH3+, graphene interlayers is parallel to the substrate and arranged between two epoxy coatings. This not only gives full play to the barrier effect of graphene, but also shielding the galvanic corrosion by avoiding direct contacting with the substrate. The results show that the composite coating prepared 10 scanning of dopamine functionalized graphene oxide has a low-frequency impedance of 1.30 x 10(9) O cm(2) after immersion in 3.5 wt% NaCl solution for 90 days, which is three orders of magnitude higher than that of pure coating, revealing remarkable long-term anticorrosion. We consider that our strategy can be readily extended to the self-alignment of a variety of two-dimensional nanofillers to facilitate the development of long-term corrosion resistant coatings. |
源URL | [http://ir.nimte.ac.cn/handle/174433/22020] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | 1.Wang, LP (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China. 2.Zhao, HC |
推荐引用方式 GB/T 7714 | Zhu, Xiaobo,Zhao, Haichao,Wang, Liping,et al. Bioinspired ultrathin graphene nanosheets sandwiched between epoxy layers for high performance of anticorrosion coatings[J]. CHEMICAL ENGINEERING JOURNAL,2021,410. |
APA | Zhu, Xiaobo,Zhao, Haichao,Wang, Liping,&Xue, Qunji.(2021).Bioinspired ultrathin graphene nanosheets sandwiched between epoxy layers for high performance of anticorrosion coatings.CHEMICAL ENGINEERING JOURNAL,410. |
MLA | Zhu, Xiaobo,et al."Bioinspired ultrathin graphene nanosheets sandwiched between epoxy layers for high performance of anticorrosion coatings".CHEMICAL ENGINEERING JOURNAL 410(2021). |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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