Engineering the interface in graphene oxide/epoxy composites using bio-based epoxy-graphene oxide nanomaterial to achieve superior anticorrosion performance
文献类型:期刊论文
作者 | Wu, Hao; Cheng, Li; Liu, Chengbao; Lan, Xijian; Zhao, Haichao |
刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
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出版日期 | 2021 |
卷号 | 587页码:755-766 |
英文摘要 | The protective performance of graphene/polymer composite coatings largely depends on the interface design in resin matrix. Herein, we report the synthesis of bio-based cardanol epoxy modified graphene oxide (GODN) nanomaterial and its application in epoxy coatings for the achievement of fine interface toward high performance anticorrosion composite coatings. The chemical composition of prepared GODN nanomaterial was investigated by FTIR, Raman and XPS spectra, respectively. The presence of cardanol epoxy attached on GO surface promotes the formation of chemical bonds between GO and epoxy resin, providing strong interfacial interaction and enhanced adhesion. Electrochemical results revealed that the GODN1%/EP composite coating exhibits high impedance (4.38 x 10(8) Omega cm(2)) even after 45 days immersion. Compared with pure EP coating, the localized corrosion reaction of GODN1%/EP coating can be inhibited under defected interface. The enhanced protective performance of GODN/EP composite coating was attributed to two aspects: (1) the impermeable GO greatly suppressed the penetration of aggressive ions and (2) the attached cardanol epoxy chains effectively improved the interfacial interaction and thus inhibited the crack propagation. (c) 2020 Elsevier Inc. All rights reserved. |
源URL | [http://ir.nimte.ac.cn/handle/174433/22065] ![]() |
专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
作者单位 | 1.Liu, CB 2.Zhao, HC (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Wu, Hao,Cheng, Li,Liu, Chengbao,et al. Engineering the interface in graphene oxide/epoxy composites using bio-based epoxy-graphene oxide nanomaterial to achieve superior anticorrosion performance[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2021,587:755-766. |
APA | Wu, Hao,Cheng, Li,Liu, Chengbao,Lan, Xijian,&Zhao, Haichao.(2021).Engineering the interface in graphene oxide/epoxy composites using bio-based epoxy-graphene oxide nanomaterial to achieve superior anticorrosion performance.JOURNAL OF COLLOID AND INTERFACE SCIENCE,587,755-766. |
MLA | Wu, Hao,et al."Engineering the interface in graphene oxide/epoxy composites using bio-based epoxy-graphene oxide nanomaterial to achieve superior anticorrosion performance".JOURNAL OF COLLOID AND INTERFACE SCIENCE 587(2021):755-766. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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