Facile synthesis and isolation of 5-hydroxymethylfurfural from diphenyl sulfoxide dagger
文献类型：期刊论文
| 作者 | Zhang, Tongtong; Hu, Yaoping; Huai, Liyuan; Gao, Zhijin; Zhang, Jian |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2021 |
| 卷号 | 23期号:9页码:3241-3245 |
| 英文摘要 | We report diphenyl sulfoxide (DPhSO) as an active, cheap and environmentally friendly solvent to facilely synthesize 5-hydroxymethylfurfural (HMF) from fructose. It acts as both the catalyst and solvent to afford nearly 100% conversion of fructose and 68.4% yield of HMF. In particular, HMF was easily extracted using water and DPhSO froze into an insoluble solid at low temperature. DPhSO was reused 6 times without significant loss of activity. The reaction mechanism of DPhSO-catalyzed HMF formation was analyzed by NMR and ESI-MS experiments and theoretical calculations. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22075]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Huai, LY 2.Zhang, J (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Zhang, Tongtong,Hu, Yaoping,Huai, Liyuan,et al. Facile synthesis and isolation of 5-hydroxymethylfurfural from diphenyl sulfoxide dagger[J]. GREEN CHEMISTRY,2021,23(9):3241-3245. |
| APA | Zhang, Tongtong,Hu, Yaoping,Huai, Liyuan,Gao, Zhijin,&Zhang, Jian.(2021).Facile synthesis and isolation of 5-hydroxymethylfurfural from diphenyl sulfoxide dagger.GREEN CHEMISTRY,23(9),3241-3245. |
| MLA | Zhang, Tongtong,et al."Facile synthesis and isolation of 5-hydroxymethylfurfural from diphenyl sulfoxide dagger".GREEN CHEMISTRY 23.9(2021):3241-3245. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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