Scalable and facile synthesis of acetal covalent adaptable networks with readily adjustable properties
文献类型：期刊论文
| 作者 | Lu, Na; Li, Qiong; Ma, Songqi; Wang, Binbo; Xu, Xiwei; Wang, Sheng; Ye, Jiale; Qiu, Jianfan; Zhu, Jin |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2021 |
| 卷号 | 147 |
| 关键词 | DEGRADABLE THERMOSETS EPOXY-RESINS POLYMERS BONDS BLOCK |
| 英文摘要 | Covalent adaptable networks (CANs) were rapidly developed to address the recycle issue of thermosets; however, facile and scalable synthesis of CANs is still a challenge. Here, we report the preparation of the acetal-based CANs with commercially available raw materials by a one-pot method without solvent, which can achieve zero atom loss over the whole process. The CANs were synthesized through a radical copolymerization of styrene (or 2-ethylhexyl methacrylate) and 2-hydroxyethyl methacrylate and an addition reaction of the hydroxyl from 2-hydroxyethyl methacrylate and a divinyl ether in one pot. The CANs could be recycled by hot-press reprocessing, and could also be degraded and regenerated into networks to achieve closed-loop recycling. In addition, the thermal and mechanical properties could be readily regulated by changing the monomers for the preparation. This work provides a scalable method to prepare acetal-based CANs, which will shorten the scientific research of CANs to industrialization. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22089]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | Ma, SQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Lu, Na,Li, Qiong,Ma, Songqi,et al. Scalable and facile synthesis of acetal covalent adaptable networks with readily adjustable properties[J]. EUROPEAN POLYMER JOURNAL,2021,147. |
| APA | Lu, Na.,Li, Qiong.,Ma, Songqi.,Wang, Binbo.,Xu, Xiwei.,...&Zhu, Jin.(2021).Scalable and facile synthesis of acetal covalent adaptable networks with readily adjustable properties.EUROPEAN POLYMER JOURNAL,147. |
| MLA | Lu, Na,et al."Scalable and facile synthesis of acetal covalent adaptable networks with readily adjustable properties".EUROPEAN POLYMER JOURNAL 147(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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