Poly(1,4-butylene-co-1,4-cyclohexanedimethylene 2,5-furandicarboxylate) copolyester: Potential bio-based engineering plastic
文献类型：期刊论文
| 作者 | Shen, Ang; Wang, Guohua; Wang, Jinggang; Zhang, Xiaoqin; Fei, Xuan; Fan, Lin; Zhu, Jin; Liu, Xiaoqing |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2021 |
| 卷号 | 147 |
| 英文摘要 | Poly(1,4-butylene-co-1,4-cyclohexanedimethylene 2,5-furandicarboxylate) (PBCFs) was synthesized from biobased 2,5-furandicarboxylic acid (FDCA), 1,4-butanediol (BDO) and 1,4-cyclohexanedimethanol (CHDM). The GPC showed that the number average molecular weight (M-n) of PBCFs were in the range of 38400-44200 g/mol and the average molecular weight (M-w) varied from 83,000 to 94,800 g/mol with the polydispersity index of 2.22-2.33. The chemical structures, compositions and sequence distributions of PBCFs were confirmed by H-1 NMR and C-13 NMR. Their thermal properties and crystallization behavior were investigated by Differential Scanning Calorimeter (DSC). Results showed that the glass transition temperature (T-g) and melting temperature (T-m) of poly(butylene 2,5-furandicarboxylate) (PBF) were increased from 38 and 171.8 degrees C to 65.8 and 211.7 degrees C for PBCF-68, respectively. Furthermore, the strength and modulus were increased from 44 and 950 MPa for PBF to 69 and 1360 MPa for PBCF-68 with the mole percentage of CHDM units of 68% in diol units. PBCFs demonstrated much better thermo-mechanical properties when compared with those of PBF, which might be used as the bio-based engineering plastic or excellent packaging materials with high transparency and good gas barrier properties. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22090]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Wang, JG 2.Liu, XQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China. 3.Zhu, J |
| 推荐引用方式 GB/T 7714 | Shen, Ang,Wang, Guohua,Wang, Jinggang,et al. Poly(1,4-butylene-co-1,4-cyclohexanedimethylene 2,5-furandicarboxylate) copolyester: Potential bio-based engineering plastic[J]. EUROPEAN POLYMER JOURNAL,2021,147. |
| APA | Shen, Ang.,Wang, Guohua.,Wang, Jinggang.,Zhang, Xiaoqin.,Fei, Xuan.,...&Liu, Xiaoqing.(2021).Poly(1,4-butylene-co-1,4-cyclohexanedimethylene 2,5-furandicarboxylate) copolyester: Potential bio-based engineering plastic.EUROPEAN POLYMER JOURNAL,147. |
| MLA | Shen, Ang,et al."Poly(1,4-butylene-co-1,4-cyclohexanedimethylene 2,5-furandicarboxylate) copolyester: Potential bio-based engineering plastic".EUROPEAN POLYMER JOURNAL 147(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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