Efficient photocatalytic hydrogen evolution over carbon supported antiperovskite cobalt zinc nitride
文献类型：期刊论文
| 作者 | Liu, Siqi; Meng, Xiangjian; Adimi, Samira; Guo, Haichuan; Qi, Weiliang; Attfield, J. Paul; Yang, Minghui |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2021 |
| 卷号 | 408 |
| 关键词 | METAL ELECTROCATALYST WATER GRAPHENE |
| 英文摘要 | Photocatalytic solar to chemical energy conversion is an important energy conversion process but suffer from low efficiency. Thus, development of efficient photocatalytic system using earth-abundant elements with low costs is highly desirable. Here, antiperovskite cobalt zinc nitride has been synthesized and coupled with carbon black (Co3ZnN/C) for visible light driven hydrogen production in an Eosin Y-sensitized system. Replacement of cobalt atom by zinc atom leads to an improved charge transfer kinetics and catalytic properties compared with Co4N. Density functional theory (DFT) calculations further reveal the adjusted electronic structure of Co3ZnN by zinc atom introducing. The lower antibonding energy states of Co3ZnN are beneficial for the hydrogen desorption. Moreover, carbon black as support effectively reduces the particle size of Co3ZnN and benefits to the electron storage and adsorption capabilities. The optimal Co3ZnN/C catalysts exhibit the H-2 evolution rate of 15.4 mu mol mg(-1) h(-1),which is over 6 times higher than that of monometallic Co4N. It is even greater than those of most of Eosin Y-sensitized systems. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22097]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Qi, WL 2.Attfield, JP (corresponding author), Univ Edinburgh, Sch Chem, Kings Bldg, Edinburgh, Midlothian, Scotland. 3.Yang, MH (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 4.Attfield, JP (corresponding author), Univ Edinburgh, Ctr Sci Extreme Condit, Kings Bldg, Edinburgh, Midlothian, Scotland. |
| 推荐引用方式 GB/T 7714 | Liu, Siqi,Meng, Xiangjian,Adimi, Samira,et al. Efficient photocatalytic hydrogen evolution over carbon supported antiperovskite cobalt zinc nitride[J]. CHEMICAL ENGINEERING JOURNAL,2021,408. |
| APA | Liu, Siqi.,Meng, Xiangjian.,Adimi, Samira.,Guo, Haichuan.,Qi, Weiliang.,...&Yang, Minghui.(2021).Efficient photocatalytic hydrogen evolution over carbon supported antiperovskite cobalt zinc nitride.CHEMICAL ENGINEERING JOURNAL,408. |
| MLA | Liu, Siqi,et al."Efficient photocatalytic hydrogen evolution over carbon supported antiperovskite cobalt zinc nitride".CHEMICAL ENGINEERING JOURNAL 408(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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