MOF Embedded and Cu Doped CeO2 Nanostructures as Efficient Catalyst for Adipic Acid Production: Green Catalysis
文献类型：期刊论文
| 作者 | Bibi, Shabahat; Pervaiz, Erum; Yang, Minghui; Rabi, Osama |
| 刊名 | CATALYSTS
 |
| 出版日期 | 2021 |
| 卷号 | 11期号:3 |
| 英文摘要 | Greatly efficient chemical processes are customarily based upon a catalyst activating the process pathway to achieve higher yields of a product with desired specifications. Catalysts capable of achieving good performance without compromising green credentials are a pre-requisite for the development of a sustainable process. In this study, CeO2 nanoparticles were tested for their catalytic activity with two different configurations, one as a hybrid of CeO2 nanoparticles with Zeolitic Immidazole Framework (ZIF-67) and second being doped Cu cations into CeO2 nanoparticles. Physicochemical and catalytic activity was investigated and compared for both systems. Each hybrid was synthesized by embedding the CeO2 nanoparticles into the microporous structure of ZIF-67, and Cu doped CeO2 nanoparticles were prepared by a facile hydrothermal route. As a catalytic test, it was employed for the oxidation of cyclohexene to adipic acid (AA) as an alternative to expensive noble metal-based catalysts. Heterogeneous ZIF-67/CeO2 found catalytical activity towards the oxidation of cyclohexene with nearly complete conversion of cyclohexene into AA under moderate and co-catalyst free reaction conditions, whereas Cu doped CeO2 nanoparticles have shown no catalytic activity towards cyclohexene conversion, depicting the advantages of the porous ZIF-67 structure and its synergistic effect with CeO2 nanoparticles. The large surface area catalyst could be a viable option for the green synthesis of many other chemicals. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22130]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | Pervaiz, E (corresponding author), Natl Univ Sci & Technol, Heterogeneous Catalysis Lab, Dept Chem Engn, Sch Chem & Mat Engn, Sect H-12, Islamabad 44000, Pakistan. |
| 推荐引用方式 GB/T 7714 | Bibi, Shabahat,Pervaiz, Erum,Yang, Minghui,et al. MOF Embedded and Cu Doped CeO2 Nanostructures as Efficient Catalyst for Adipic Acid Production: Green Catalysis[J]. CATALYSTS,2021,11(3). |
| APA | Bibi, Shabahat,Pervaiz, Erum,Yang, Minghui,&Rabi, Osama.(2021).MOF Embedded and Cu Doped CeO2 Nanostructures as Efficient Catalyst for Adipic Acid Production: Green Catalysis.CATALYSTS,11(3). |
| MLA | Bibi, Shabahat,et al."MOF Embedded and Cu Doped CeO2 Nanostructures as Efficient Catalyst for Adipic Acid Production: Green Catalysis".CATALYSTS 11.3(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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