High-performance bio-based epoxies from ferulic acid and furfuryl alcohol: synthesis and properties
文献类型：期刊论文
| 作者 | Ye, Jiale; Ma, Songqi; Wang, Binbo; Chen, Qingming; Huang, Kaifeng; Xu, Xiwei; Li, Qiong; Wang, Sheng; Lu, Na; Zhu, Jin |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2021 |
| 卷号 | 23期号:4页码:1772-1781 |
| 英文摘要 | The lignin derivative ferulic acid was directly functionalized to diepoxy which could be co-cross-linked with furfuryl alcohol-derived monoepoxy to achieve high-performance bio-based thermosets. The development of high-performance bio-based epoxy as a sustainable alternative to fossil-sourced bisphenol A epoxy has great significance. In this work, ferulic acid-based diepoxy (FAE) was facilely synthesized through a direct reaction with epichlorohydrin. After cross-linking, its thermal and mechanical properties are comparable with or even higher than those of bisphenol A epoxy. The carbon-carbon double bond in the framework of the FAE was also exploited to further upgrade its properties via the Diels-Alder reaction with a synthesized glycidyl ether of furfuryl alcohol (GEFA). The chemical structures of FAE and GEFA, curing kinetics, and the Diels-Alder reaction were characterized in detail. The glass transition temperature of FAE-GEFA systems reached similar to 250 degrees C. This work provides a simple way to achieve high-performance thermosets from ferulic acid, and also offers a promising sustainable alternative to bisphenol A epoxy. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22175]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | Ma, SQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat, Lab Polymers & Composites, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Ye, Jiale,Ma, Songqi,Wang, Binbo,et al. High-performance bio-based epoxies from ferulic acid and furfuryl alcohol: synthesis and properties[J]. GREEN CHEMISTRY,2021,23(4):1772-1781. |
| APA | Ye, Jiale.,Ma, Songqi.,Wang, Binbo.,Chen, Qingming.,Huang, Kaifeng.,...&Zhu, Jin.(2021).High-performance bio-based epoxies from ferulic acid and furfuryl alcohol: synthesis and properties.GREEN CHEMISTRY,23(4),1772-1781. |
| MLA | Ye, Jiale,et al."High-performance bio-based epoxies from ferulic acid and furfuryl alcohol: synthesis and properties".GREEN CHEMISTRY 23.4(2021):1772-1781. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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