High-Temperature Synthesis of a Uranyl Peroxo Complex Facilitated by Hydrothermally In Situ Formed Organic Peroxide
文献类型：期刊论文
| 作者 | Mei, Lei; Wu, Qun-yan; Wu, Si; Geng, Jun-Shan; Liu, Ya-lan; Hu, Kong-qiu; Liu, Yi-chuan; Zhang, Zhi-hui; Liang, Yuan-yuan; Chai, Zhi-fang |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2021 |
| 卷号 | 60期号:4页码:2133-2137 |
| 英文摘要 | Because H2O2 is thermally unstable, it seems to be difficult to synthesize peroxides at elevated temperatures. We describe here the in situ generation of peroxide that is incorporated in a new uranyl peroxo complex, HT-UPO1, through the hydrothermal treatment of uranyl nitrate at 150 degrees C in the presence of organic ligands. In this novel process, a highly conjugated aromatic carboxylate linker, (E)-4-[2-(pyridin-4-yl)vinyl]benzoic acid (HPyVB), plays a crucial role by inducing the reduction of oxygen in air to form peroxide in situ and coordinating with uranyl to promote the preferred formation of thermally stable HT-UPO1. This work expands our knowledge on the speciation and chemistry of uranyl peroxide compounds and also sheds light on the possibility of their synthesis under more harsh conditions. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22190]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | Shi, WQ (corresponding author), Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Mei, Lei,Wu, Qun-yan,Wu, Si,et al. High-Temperature Synthesis of a Uranyl Peroxo Complex Facilitated by Hydrothermally In Situ Formed Organic Peroxide[J]. INORGANIC CHEMISTRY,2021,60(4):2133-2137. |
| APA | Mei, Lei.,Wu, Qun-yan.,Wu, Si.,Geng, Jun-Shan.,Liu, Ya-lan.,...&Shi, Wei-qun.(2021).High-Temperature Synthesis of a Uranyl Peroxo Complex Facilitated by Hydrothermally In Situ Formed Organic Peroxide.INORGANIC CHEMISTRY,60(4),2133-2137. |
| MLA | Mei, Lei,et al."High-Temperature Synthesis of a Uranyl Peroxo Complex Facilitated by Hydrothermally In Situ Formed Organic Peroxide".INORGANIC CHEMISTRY 60.4(2021):2133-2137. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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