High-Temperature Resistant Polyborosilazanes with Tailored Structures
文献类型：期刊论文
| 作者 | Wang, Bijie; Chen, Ke; Li, Tianhao; Sun, Xun; Liu, Ming; Yang, Lingwei; Hu, Xiao (Matthew); Xu, Jian; He, Liu; Huang, Qing |
| 刊名 | POLYMERS
 |
| 出版日期 | 2021 |
| 卷号 | 13期号:3 |
| 英文摘要 | Boron-containing organosilicon polymers are widely used under harsh environments as preceramic polymers for advanced ceramics fabrication. However, harmful chemicals released during synthesis and the complex synthesis routes have limited their applications. To solve the problems, a two-component route was adopted to synthesize cross-linked boron-containing silicone polymer (CPBCS) via a solventless process. The boron content and CPBCSs' polymeric structures could be readily tuned through controlling the ratio of multifunctional boron hybrid silazane monomers (BSZ12) and poly[imino(methylsilylene)]. The CPBCSs showed high thermal stability and good mechanical properties. The CPBCS with Si-H/C=C ratio of 10:1 showed 75 wt% char yields at 1000 degrees C in argon, and the heat release capacity (HRC) and total heat release (THR) are determined to be 37.9 J/g K and 6.2 KJ/g, demonstrating high thermal stability and flame retardancy. The reduced modulus and hardness of CPBCS are 0.30 GPa and 2.32 GPa, respectively. The novel polysilazanes can be potentially used under harsh environments, such as high temperatures or fire hazards. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22238]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Song, YJ (corresponding author), Qianwan Inst CNiTECH, Ningbo 315336, Peoples R China. 2.Jiang, LB (corresponding author), Guangxi Univ, Guangxi Key Lab Petrochem Resource Proc & Proc In, Sch Chem & Chem Engn, Nanning 530004, Peoples R China. 3.Song, YJ (corresponding author), Chinese Acad Sci, Engn Lab Adv Energy Mat, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wang, Bijie,Chen, Ke,Li, Tianhao,et al. High-Temperature Resistant Polyborosilazanes with Tailored Structures[J]. POLYMERS,2021,13(3). |
| APA | Wang, Bijie.,Chen, Ke.,Li, Tianhao.,Sun, Xun.,Liu, Ming.,...&Song, Yujie.(2021).High-Temperature Resistant Polyborosilazanes with Tailored Structures.POLYMERS,13(3). |
| MLA | Wang, Bijie,et al."High-Temperature Resistant Polyborosilazanes with Tailored Structures".POLYMERS 13.3(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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