Highly conductive C12A7:e(-) electride nanoparticles as an electron donor type promoter to P25 for enhancing photocatalytic hydrogen evolution
文献类型：期刊论文
| 作者 | Hu, Qiao; Tan, Ruiqin; Li, Jia; Song, Weijie |
| 刊名 | JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
 |
| 出版日期 | 2021 |
| 卷号 | 149 |
| 关键词 | H-2 EVOLUTION G-C3N4 NANOSHEETS STABLE ELECTRIDE COCATALYST WATER TIO2 CDS DECOMPOSITION ENHANCEMENT PERFORMANCE |
| 英文摘要 | In this work, we report a comprehensive investigation on the catalytic performance and mechanism of mayenite electride [Ca24Al28O64](4+)(O2-)(2-x) (e(-))(2x) (C12A7:e(-)) as an electron donor type promoter to P25 in hydrogen production from water. Herein, the C12A7:e(-)-P25 composites were prepared by simply mechanical mixing method. The optimum H-2 evolution rate reached 663 mu mol h(-1) g(-1) which was 43.9 times higher than that of pure P25, when 0.25 wt% C12A7:e(-) was added. Mott-Schottky plots and X-ray photoelectron spectroscopic results confirmed the injection of electrons encaged in C12A7:e(-) to the conduction band of P25. Surface photovoltage measurements and photoluminescence results showed that the introduction of C12A7:e(-) promoted the efficient separation of photogenerated electron-hole pairs of P25, which illustrated the formation of built-in electric field from P25 to C12A7:e(-) due to the difference in work function. The present work provides new promoter choices for photocatalytic studies. |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/22247]  |
| 专题 | 中国科学院宁波材料技术与工程研究所 2021专题_期刊论文 |
| 作者单位 | 1.Li, J 2.Song, WJ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Hu, Qiao,Tan, Ruiqin,Li, Jia,et al. Highly conductive C12A7:e(-) electride nanoparticles as an electron donor type promoter to P25 for enhancing photocatalytic hydrogen evolution[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,2021,149. |
| APA | Hu, Qiao,Tan, Ruiqin,Li, Jia,&Song, Weijie.(2021).Highly conductive C12A7:e(-) electride nanoparticles as an electron donor type promoter to P25 for enhancing photocatalytic hydrogen evolution.JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,149. |
| MLA | Hu, Qiao,et al."Highly conductive C12A7:e(-) electride nanoparticles as an electron donor type promoter to P25 for enhancing photocatalytic hydrogen evolution".JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 149(2021). |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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